Macromolecular theory of solvation and structure in mixtures of colloids and polymers

Fuchs, Matthias; Schweizer, Kenneth S.

Macromolecular theory of solvation and structure in mixtures of colloids and polymers

Dateien

Macromolecular_theory_of_solvation_and_structure_in_mixtures_of_colloids_and_polymers.pdfGröße: 270.69 KBDownloads: 377

Datum

2001

Autor:innen

Fuchs, Matthias

Schweizer, Kenneth S.

Open Access-Veröffentlichung

Open Access Green

Sammlungen

Physik

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Physical Review E. 2001, 64, 21514. Available under: doi: 10.1103/PhysRevE.64.021514

Zusammenfassung

The structural and thermodynamic properties of mixtures of colloidal spheres and nonadsorbing polymer chains are studied within a general two-component macromolecular liquid state approach applicable for all size asymmetry ratios. The dilute limits, when one of the components is at infinite dilution but the other concentrated, are presented and compared to field theory and to models that replace polymer coils with spheres. Whereas the derived analytical results compare well, qualitatively and quantitatively, with mean-field scaling laws where available, important differences from effective sphere approaches are found for large polymer sizes or semidilute concentrations.

Fachgebiet (DDC)

530 Physik

Zitieren

ISO 690

FUCHS, Matthias, Kenneth S. SCHWEIZER, 2001. Macromolecular theory of solvation and structure in mixtures of colloids and polymers. In: Physical Review E. 2001, 64, 21514. Available under: doi: 10.1103/PhysRevE.64.021514

BibTex

@article{Fuchs2001Macro-5158,
  year={2001},
  doi={10.1103/PhysRevE.64.021514},
  title={Macromolecular theory of solvation and structure in mixtures of colloids and polymers},
  volume={64},
  journal={Physical Review E},
  author={Fuchs, Matthias and Schweizer, Kenneth S.},
  note={Article Number: 21514}
}

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