[(C5(CH3)5)CoCl]2(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metal-metal bond
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1988
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Journal of Organometallic Chemistry. 1988, 340(2), pp. 249-256. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(88)80080-9
Zusammenfassung
The compounds (C5(CH3)5)Co(NO)X (X = Cl, Br, I) have been prepared by reaction of [(C5(CH3)5)Co]2(μ-NO)2 with the appropriate dihalogen X2. Either by spontaneous decomposition or by addition of half an equivalent of [(C5(CH3)5)-CoCl]2(μ-Cl)2, the chloro derivative forms the binuclear complex [(C5(CH3)5)-CoCl]2(μ-NO)(μ-Cl), the crystal structure of which indicates the presence of a nitrosyl bridge without a metal-metal bond.
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540 Chemie
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STRAUSS, R. Christian, Egbert KELLER, Hans-Herbert BRINTZINGER, 1988. [(C5(CH3)5)CoCl]2(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metal-metal bond. In: Journal of Organometallic Chemistry. 1988, 340(2), pp. 249-256. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(88)80080-9BibTex
@article{Strauss1988binuc-23973, year={1988}, doi={10.1016/0022-328X(88)80080-9}, title={[(C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)CoCl]<sub>2</sub>(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metal-metal bond}, number={2}, volume={340}, issn={0022-328X}, journal={Journal of Organometallic Chemistry}, pages={249--256}, author={Strauss, R. Christian and Keller, Egbert and Brintzinger, Hans-Herbert} }
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