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[(C5(CH3)5)CoCl]2(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metal-metal bond

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Strauss_etall-0022328X88800809.pdf
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1988

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Strauss, R. Christian
Keller, Egbert

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http://nbn-resolving.de/urn:nbn:de:bsz:352-239738
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https://doi.org/10.1016/0022-328X(88)80080-9
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Journal of Organometallic Chemistry. 1988, 340(2), pp. 249-256. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(88)80080-9

Zusammenfassung

The compounds (C5(CH3)5)Co(NO)X (X = Cl, Br, I) have been prepared by reaction of [(C5(CH3)5)Co]2(μ-NO)2 with the appropriate dihalogen X2. Either by spontaneous decomposition or by addition of half an equivalent of [(C5(CH3)5)-CoCl]2(μ-Cl)2, the chloro derivative forms the binuclear complex [(C5(CH3)5)-CoCl]2(μ-NO)(μ-Cl), the crystal structure of which indicates the presence of a nitrosyl bridge without a metal-metal bond.

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540 Chemie

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ISO 690STRAUSS, R. Christian, Egbert KELLER, Hans-Herbert BRINTZINGER, 1988. [(C5(CH3)5)CoCl]2(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metal-metal bond. In: Journal of Organometallic Chemistry. 1988, 340(2), pp. 249-256. ISSN 0022-328X. eISSN 1872-8561. Available under: doi: 10.1016/0022-328X(88)80080-9
BibTex
@article{Strauss1988binuc-23973,
  year={1988},
  doi={10.1016/0022-328X(88)80080-9},
  title={[(C<sub>5</sub>(CH<sub>3</sub>)<sub>5</sub>)CoCl]<sub>2</sub>(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metal-metal bond},
  number={2},
  volume={340},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={249--256},
  author={Strauss, R. Christian and Keller, Egbert and Brintzinger, Hans-Herbert}
}
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    <dcterms:title>[(C&lt;sub&gt;5&lt;/sub&gt;(CH&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;5&lt;/sub&gt;)CoCl]&lt;sub&gt;2&lt;/sub&gt;(μ-NO)(μ-Cl), a binuclear complex containing a nitrosyl bridge without a metal-metal bond</dcterms:title>
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