Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions
Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions
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2000
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Yamamoto, Hisashi
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Angewandte Chemie International Edition ; 39 (2000), 1. - pp. 178-181. - ISSN 1433-7851. - eISSN 1521-3773
Abstract
R2AlNTf2 (2 – 5 mol%) are highly efficient and versatile and are suitable promoters for the allylation and pentadienylation of aldehydes, aldol reactions, aldol cross-coupling of ketones, and Michael additions (several products are shown). Furthermore, they can be converted into chemoselective Lewis acids. Tf=trifluoromethanesulfonyl.
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540 Chemistry
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MARX, Andreas, Hisashi YAMAMOTO, 2000. Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions. In: Angewandte Chemie International Edition. 39(1), pp. 178-181. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-WBibTex
@article{Marx2000-01-03Alumi-33858, year={2000}, doi={10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-W}, title={Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions}, number={1}, volume={39}, issn={1433-7851}, journal={Angewandte Chemie International Edition}, pages={178--181}, author={Marx, Andreas and Yamamoto, Hisashi} }
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