Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions

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2000
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Yamamoto, Hisashi
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Angewandte Chemie International Edition. 2000, 39(1), pp. 178-181. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-W
Zusammenfassung

R2AlNTf2 (2 – 5 mol%) are highly efficient and versatile and are suitable promoters for the allylation and pentadienylation of aldehydes, aldol reactions, aldol cross-coupling of ketones, and Michael additions (several products are shown). Furthermore, they can be converted into chemoselective Lewis acids. Tf=trifluoromethanesulfonyl.

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ISO 690MARX, Andreas, Hisashi YAMAMOTO, 2000. Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions. In: Angewandte Chemie International Edition. 2000, 39(1), pp. 178-181. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-W
BibTex
@article{Marx2000-01-03Alumi-33858,
  year={2000},
  doi={10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-W},
  title={Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions},
  number={1},
  volume={39},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={178--181},
  author={Marx, Andreas and Yamamoto, Hisashi}
}
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