Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions

Marx, Andreas; Yamamoto, Hisashi

Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions

Files

Marx_0-329637.pdf(832.02 KB)

Date

2000

Authors

Marx, Andreas

Yamamoto, Hisashi

Publication type

Journal article

Publication status

Published

Published in

Angewandte Chemie International Edition ; 39 (2000), 1. - pp. 178-181. - ISSN 1433-7851. - eISSN 1521-3773

Abstract

R₂AlNTf₂ (2 – 5 mol%) are highly efficient and versatile and are suitable promoters for the allylation and pentadienylation of aldehydes, aldol reactions, aldol cross-coupling of ketones, and Michael additions (several products are shown). Furthermore, they can be converted into chemoselective Lewis acids. Tf=trifluoromethanesulfonyl.

Subject (DDC)

540 Chemistry

Cite This

ISO 690

MARX, Andreas, Hisashi YAMAMOTO, 2000. Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions. In: Angewandte Chemie International Edition. 39(1), pp. 178-181. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-W

BibTex

@article{Marx2000-01-03Alumi-33858,
  year={2000},
  doi={10.1002/(SICI)1521-3773(20000103)39:1<178::AID-ANIE178>3.0.CO;2-W},
  title={Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions},
  number={1},
  volume={39},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={178--181},
  author={Marx, Andreas and Yamamoto, Hisashi}
}

RDF

<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/33858">
    <dc:language>eng</dc:language>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/33858"/>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/33858/1/Marx_0-329637.pdf"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/33858/1/Marx_0-329637.pdf"/>
    <dc:contributor>Yamamoto, Hisashi</dc:contributor>
    <dc:creator>Marx, Andreas</dc:creator>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-05-10T09:45:29Z</dcterms:available>
    <dcterms:abstract xml:lang="eng">R&lt;sub&gt;2&lt;/sub&gt;AlNTf&lt;sub&gt;2&lt;/sub&gt; (2 – 5 mol%) are highly efficient and versatile and are suitable promoters for the allylation and pentadienylation of aldehydes, aldol reactions, aldol cross-coupling of ketones, and Michael additions (several products are shown). Furthermore, they can be converted into chemoselective Lewis acids. Tf=trifluoromethanesulfonyl.</dcterms:abstract>
    <dc:creator>Yamamoto, Hisashi</dc:creator>
    <dcterms:title>Aluminum Bis(trifluoromethylsulfonyl)amides : New Highly Efficient and Remarkably Versatile Catalysts for C - C Bond Formation Reactions</dcterms:title>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dc:rights>terms-of-use</dc:rights>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2016-05-10T09:45:29Z</dc:date>
    <dc:contributor>Marx, Andreas</dc:contributor>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:issued>2000-01-03</dcterms:issued>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
  </rdf:Description>
</rdf:RDF>

Bibliography of Konstanz

No