Benzene complexes in cyclopentadienylcobalt(I) reaction systems
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1981
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Journal of Organometallic Chemistry. 1981, 206(1), pp. C4-C6. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)93472-7
Zusammenfassung
Photolysis of (C5H5)Co(CO)2 in an aromatic solvent, such as benzene, toluene or s-mesitylene generates the corresponding (C5H5)Co(arene) and (C5H5)Co(arene)2 complexes. The benzene complex (C5H5)Co(C6H6) reacts with 2-butyne to form the hexamethyl benzene derivative (C5H5)Co(C6(CH3)6) but does not catalyze the formation of free hexamethylbenzene from excess 2-butyne.
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540 Chemie
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LEE, Wai-Sun, Johnson D. KOOLA, Hans-Herbert BRINTZINGER, 1981. Benzene complexes in cyclopentadienylcobalt(I) reaction systems. In: Journal of Organometallic Chemistry. 1981, 206(1), pp. C4-C6. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)93472-7BibTex
@article{Lee1981Benze-23957,
year={1981},
doi={10.1016/S0022-328X(00)93472-7},
title={Benzene complexes in cyclopentadienylcobalt(I) reaction systems},
number={1},
volume={206},
issn={0022-328X},
journal={Journal of Organometallic Chemistry},
pages={C4--C6},
author={Lee, Wai-Sun and Koola, Johnson D. and Brintzinger, Hans-Herbert}
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<dcterms:abstract xml:lang="eng">Photolysis of (C<sub>5</sub>H<sub>5</sub>)Co(CO)<sub>2</sub> in an aromatic solvent, such as benzene, toluene or s-mesitylene generates the corresponding (C<sub>5</sub>H<sub>5</sub>)Co(arene) and (C<sub>5</sub>H<sub>5</sub>)Co(arene)<sub>2</sub> complexes. The benzene complex (C<sub>5</sub>H<sub>5</sub>)Co(C<sub>6</sub>H<sub>6</sub>) reacts with 2-butyne to form the hexamethyl benzene derivative (C<sub>5</sub>H<sub>5</sub>)Co(C<sub>6</sub>(CH<sub>3</sub>)<sub>6</sub>) but does not catalyze the formation of free hexamethylbenzene from excess 2-butyne.</dcterms:abstract>
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