Publikation:

Microalgae lipids as a feedstock for the production of benzene

Lade...
Vorschaubild

Dateien

Pingen_2-pvan9egn5g9n9.pdf
Pingen_2-pvan9egn5g9n9.pdfGröße: 143.81 KBDownloads: 429

Datum

2018

Herausgeber:innen

Kontakt

ISSN der Zeitschrift

Electronic ISSN

ISBN

Bibliografische Daten

Verlag

Schriftenreihe

Auflagebezeichnung

DOI (zitierfähiger Link)
ArXiv-ID

Internationale Patentnummer

Angaben zur Forschungsförderung

Projekt

Open Access-Veröffentlichung
Open Access Green
Core Facility der Universität Konstanz

Gesperrt bis

Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Green Chemistry. 2018, 20(8), pp. 1874-1878. ISSN 1463-9262. eISSN 1463-9270. Available under: doi: 10.1039/c8gc00423d

Zusammenfassung

A two-step one-pot synthesis of benzene from the five-fold unsaturated fatty acid eicosapentaenoic acid (EPA), a component of microalgae oils, is presented. By a sequence of olefin metathesis and the catalytic dehydrogenation of the resulting 1,4-cyclohexadiene, two equivalents of benzene are effectively formed per EPA substrate molecule. As the only major by-products, 5-octenoic acid and 5-decenedioic acid are formed. Performing the dehydrogenation step under hydrogen pressure results in the formation of their saturated analogues, sebacic acid and octanoic acid, both desirable products, while the simultaneous dehydrogenation step to benzene is not hampered.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Konferenz

Rezension
undefined / . - undefined, undefined

Forschungsvorhaben

Organisationseinheiten

Zeitschriftenheft

Zugehörige Datensätze in KOPS

Zitieren

ISO 690PINGEN, Dennis, Julia ZIMMERER, Nele KLINKENBERG, Stefan MECKING, 2018. Microalgae lipids as a feedstock for the production of benzene. In: Green Chemistry. 2018, 20(8), pp. 1874-1878. ISSN 1463-9262. eISSN 1463-9270. Available under: doi: 10.1039/c8gc00423d
BibTex
@article{Pingen2018Micro-42418,
  year={2018},
  doi={10.1039/c8gc00423d},
  title={Microalgae lipids as a feedstock for the production of benzene},
  number={8},
  volume={20},
  issn={1463-9262},
  journal={Green Chemistry},
  pages={1874--1878},
  author={Pingen, Dennis and Zimmerer, Julia and Klinkenberg, Nele and Mecking, Stefan}
}
RDF
<rdf:RDF
    xmlns:dcterms="http://purl.org/dc/terms/"
    xmlns:dc="http://purl.org/dc/elements/1.1/"
    xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
    xmlns:bibo="http://purl.org/ontology/bibo/"
    xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
    xmlns:foaf="http://xmlns.com/foaf/0.1/"
    xmlns:void="http://rdfs.org/ns/void#"
    xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > 
  <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/42418">
    <dc:contributor>Pingen, Dennis</dc:contributor>
    <dcterms:title>Microalgae lipids as a feedstock for the production of benzene</dcterms:title>
    <dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
    <foaf:homepage rdf:resource="http://localhost:8080/"/>
    <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2018-05-23T09:08:53Z</dcterms:available>
    <dc:contributor>Klinkenberg, Nele</dc:contributor>
    <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/42418/1/Pingen_2-pvan9egn5g9n9.pdf"/>
    <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
    <dc:creator>Pingen, Dennis</dc:creator>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/52"/>
    <dc:creator>Mecking, Stefan</dc:creator>
    <dcterms:issued>2018</dcterms:issued>
    <dc:contributor>Mecking, Stefan</dc:contributor>
    <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2018-05-23T09:08:53Z</dc:date>
    <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <bibo:uri rdf:resource="https://kops.uni-konstanz.de/handle/123456789/42418"/>
    <dc:rights>terms-of-use</dc:rights>
    <dc:creator>Klinkenberg, Nele</dc:creator>
    <dcterms:abstract xml:lang="eng">A two-step one-pot synthesis of benzene from the five-fold unsaturated fatty acid eicosapentaenoic acid (EPA), a component of microalgae oils, is presented. By a sequence of olefin metathesis and the catalytic dehydrogenation of the resulting 1,4-cyclohexadiene, two equivalents of benzene are effectively formed per EPA substrate molecule. As the only major by-products, 5-octenoic acid and 5-decenedioic acid are formed. Performing the dehydrogenation step under hydrogen pressure results in the formation of their saturated analogues, sebacic acid and octanoic acid, both desirable products, while the simultaneous dehydrogenation step to benzene is not hampered.</dcterms:abstract>
    <dc:creator>Zimmerer, Julia</dc:creator>
    <dc:language>eng</dc:language>
    <dc:contributor>Zimmerer, Julia</dc:contributor>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/52"/>
    <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
    <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/42418/1/Pingen_2-pvan9egn5g9n9.pdf"/>
  </rdf:Description>
</rdf:RDF>

Interner Vermerk

xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter

Kontakt
URL der Originalveröffentl.

Prüfdatum der URL

Prüfungsdatum der Dissertation

Finanzierungsart

Kommentar zur Publikation

Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
Begutachtet
Ja
Diese Publikation teilen