Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity

dc.contributor.authorAmirkhanov, Oleksiy V.
dc.contributor.authorMoroz, Olesia V.
dc.contributor.authorZnovjyak, Kateryna O.
dc.contributor.authorSilva, Tetiana Yu.
dc.contributor.authorPenkova, Larysa V.
dc.contributor.authorYushchenko, Tetyana
dc.contributor.authorSzyrwiel, Lukasz
dc.contributor.authorKonovalova, Irina S.
dc.contributor.authorDyakonenko, Viktoriya
dc.contributor.authorShishkin, Oleg V.
dc.contributor.authorAmirkhanov, Vadimir M.
dc.date.accessioned2015-01-21T15:31:21Z
dc.date.available2015-01-21T15:31:21Z
dc.date.issued2014eng
dc.description.abstractThe reaction of Salen-like ZnII and NiII precursors with carbacylamidophosphate lanthanide moieties yields six new types of 3d–4f compounds. The complexes were characterized by means of 1H, 31P NMR and IR spectroscopy, elemental analysis, ESI mass spectrometry, and X-ray diffraction analysis. Depending on the Schiff base ligands, the NiII ion adopts either a square-planar or an octahedral geometry, whereas the ZnII ion has a tetragonal-pyramidal geometry. The coordination number of lanthanides is nine or ten. Hydrolytic activities of some heterobimetallic Zn–Ln and Ni–Ln coordination compounds in the reaction of intramolecular hydrolytic degradation of the 2-(hydroxypropyl)-p-nitrophenyl phosphate were investigated.eng
dc.description.versionpublished
dc.identifier.doi10.1002/ejic.201402224eng
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/29582
dc.language.isoengeng
dc.subjectHeterometallic complexes, ­Kinetics, Lanthanide, N,O-ligands, Structure elucidationeng
dc.subject.ddc540eng
dc.titleHeterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activityeng
dc.typeJOURNAL_ARTICLEeng
dspace.entity.typePublication
kops.citation.bibtex
@article{Amirkhanov2014Heter-29582,
  year={2014},
  doi={10.1002/ejic.201402224},
  title={Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity},
  number={23},
  volume={2014},
  issn={0009-2940},
  journal={European Journal of Inorganic Chemistry},
  pages={3720--3730},
  author={Amirkhanov, Oleksiy V. and Moroz, Olesia V. and Znovjyak, Kateryna O. and Silva, Tetiana Yu. and Penkova, Larysa V. and Yushchenko, Tetyana and Szyrwiel, Lukasz and Konovalova, Irina S. and Dyakonenko, Viktoriya and Shishkin, Oleg V. and Amirkhanov, Vadimir M.}
}
kops.citation.iso690AMIRKHANOV, Oleksiy V., Olesia V. MOROZ, Kateryna O. ZNOVJYAK, Tetiana Yu. SILVA, Larysa V. PENKOVA, Tetyana YUSHCHENKO, Lukasz SZYRWIEL, Irina S. KONOVALOVA, Viktoriya DYAKONENKO, Oleg V. SHISHKIN, Vadimir M. AMIRKHANOV, 2014. Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity. In: European Journal of Inorganic Chemistry. 2014, 2014(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224deu
kops.citation.iso690AMIRKHANOV, Oleksiy V., Olesia V. MOROZ, Kateryna O. ZNOVJYAK, Tetiana Yu. SILVA, Larysa V. PENKOVA, Tetyana YUSHCHENKO, Lukasz SZYRWIEL, Irina S. KONOVALOVA, Viktoriya DYAKONENKO, Oleg V. SHISHKIN, Vadimir M. AMIRKHANOV, 2014. Heterobinuclear Zn-Ln and Ni-Ln Complexes with Schiff-Base and Carbacylamidophosphate Ligands : Synthesis, Crystal Structures, and Catalytic Activity. In: European Journal of Inorganic Chemistry. 2014, 2014(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224eng
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kops.sourcefieldEuropean Journal of Inorganic Chemistry. 2014, <b>2014</b>(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224deu
kops.sourcefield.plainEuropean Journal of Inorganic Chemistry. 2014, 2014(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224deu
kops.sourcefield.plainEuropean Journal of Inorganic Chemistry. 2014, 2014(23), pp. 3720-3730. ISSN 0009-2940. eISSN 1099-0682. Available under: doi: 10.1002/ejic.201402224eng
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source.periodicalTitleEuropean Journal of Inorganic Chemistryeng
temp.internal.duplicates<p>Keine Dubletten gefunden. Letzte Überprüfung: 17.11.2014 16:17:37</p>deu

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