Unidirectional Real-Time Photoswitching of Diarylethene Molecular Monolayer Junctions with Multilayer Graphene Electrodes
| dc.contributor.author | Koo, Jeongmin | |
| dc.contributor.author | Jang, Yeonsik | |
| dc.contributor.author | Martin, León | |
| dc.contributor.author | Kim, Dongku | |
| dc.contributor.author | Jeong, Hyunhak | |
| dc.contributor.author | Kang, Kehoon | |
| dc.contributor.author | Lee, Woocheol | |
| dc.contributor.author | Kim, Junwoo | |
| dc.contributor.author | Hwang, Wang-Taek | |
| dc.contributor.author | Xiang, Dong | |
| dc.contributor.author | Scheer, Elke | |
| dc.contributor.author | Kabdulov, Mikhail | |
| dc.contributor.author | Huhn, Thomas | |
| dc.contributor.author | Pauly, Fabian | |
| dc.contributor.author | Lee, Takhee | |
| dc.date.accessioned | 2019-03-25T12:00:05Z | |
| dc.date.available | 2019-03-25T12:00:05Z | |
| dc.date.issued | 2019-03-27 | |
| dc.description.abstract | We fabricate and characterize vertical molecular junctions consisting of self-assembled monolayers (SAMs) of diarylethene (DAE) contacted by a multilayer graphene (MLG) electrode on the top and gold on the bottom. The DAE molecular junctions show two stable electrical states, a closed state (high conductance) or an open state (low conductance), which are created upon illumination with UV or visible light, respectively. For the Au-DAE-MLG junction structure, we observe that the current levels between the two conductance states are separated by two orders of magnitude. However, in a real-time measurement, we observe only unidirectional switching behavior from the open to the closed state. | eng |
| dc.description.version | published | eng |
| dc.identifier.doi | 10.1021/acsami.8b19372 | eng |
| dc.identifier.pmid | 30821955 | eng |
| dc.identifier.uri | https://kops.uni-konstanz.de/handle/123456789/45546 | |
| dc.language.iso | eng | eng |
| dc.rights | terms-of-use | |
| dc.rights.uri | https://rightsstatements.org/page/InC/1.0/ | |
| dc.subject | molecular electronics, photoswitching, diarylethene, self-assembled monolayer, graphene electrode | eng |
| dc.subject.ddc | 530 | eng |
| dc.title | Unidirectional Real-Time Photoswitching of Diarylethene Molecular Monolayer Junctions with Multilayer Graphene Electrodes | eng |
| dc.type | JOURNAL_ARTICLE | eng |
| dspace.entity.type | Publication | |
| kops.citation.bibtex | @article{Koo2019-03-27Unidi-45546,
year={2019},
doi={10.1021/acsami.8b19372},
title={Unidirectional Real-Time Photoswitching of Diarylethene Molecular Monolayer Junctions with Multilayer Graphene Electrodes},
number={12},
volume={11},
issn={1944-8244},
journal={ACS applied materials & interfaces},
pages={11645--11653},
author={Koo, Jeongmin and Jang, Yeonsik and Martin, León and Kim, Dongku and Jeong, Hyunhak and Kang, Kehoon and Lee, Woocheol and Kim, Junwoo and Hwang, Wang-Taek and Xiang, Dong and Scheer, Elke and Kabdulov, Mikhail and Huhn, Thomas and Pauly, Fabian and Lee, Takhee}
} | |
| kops.citation.iso690 | KOO, Jeongmin, Yeonsik JANG, León MARTIN, Dongku KIM, Hyunhak JEONG, Kehoon KANG, Woocheol LEE, Junwoo KIM, Wang-Taek HWANG, Dong XIANG, Elke SCHEER, Mikhail KABDULOV, Thomas HUHN, Fabian PAULY, Takhee LEE, 2019. Unidirectional Real-Time Photoswitching of Diarylethene Molecular Monolayer Junctions with Multilayer Graphene Electrodes. In: ACS applied materials & interfaces. 2019, 11(12), pp. 11645-11653. ISSN 1944-8244. eISSN 1944-8252. Available under: doi: 10.1021/acsami.8b19372 | deu |
| kops.citation.iso690 | KOO, Jeongmin, Yeonsik JANG, León MARTIN, Dongku KIM, Hyunhak JEONG, Kehoon KANG, Woocheol LEE, Junwoo KIM, Wang-Taek HWANG, Dong XIANG, Elke SCHEER, Mikhail KABDULOV, Thomas HUHN, Fabian PAULY, Takhee LEE, 2019. Unidirectional Real-Time Photoswitching of Diarylethene Molecular Monolayer Junctions with Multilayer Graphene Electrodes. In: ACS applied materials & interfaces. 2019, 11(12), pp. 11645-11653. ISSN 1944-8244. eISSN 1944-8252. Available under: doi: 10.1021/acsami.8b19372 | eng |
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<dcterms:abstract xml:lang="eng">We fabricate and characterize vertical molecular junctions consisting of self-assembled monolayers (SAMs) of diarylethene (DAE) contacted by a multilayer graphene (MLG) electrode on the top and gold on the bottom. The DAE molecular junctions show two stable electrical states, a closed state (high conductance) or an open state (low conductance), which are created upon illumination with UV or visible light, respectively. For the Au-DAE-MLG junction structure, we observe that the current levels between the two conductance states are separated by two orders of magnitude. However, in a real-time measurement, we observe only unidirectional switching behavior from the open to the closed state.</dcterms:abstract>
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