Zirconium-Allyl Complexes as Resting States in Zirconocene-Catalyzed α-Olefin Polymerization

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2015
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Panchenko, Valentina N.
Babushkin, Dmitrii E.
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Macromolecular Rapid Communications. 2015, 36(2), pp. 249-253. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201400444
Zusammenfassung

UV-vis spectroscopic data indicate that zirconocene cations with Zr-bound allylic chain ends are generally formed during olefin polymerization with zirconocene catalysts. The rates and extent of their formation and of their re-conversion to the initial pre-catalyst cations depend on the types of zirconocene complexes and activators used.

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540 Chemie
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allyl complexes, catalysis, metallocene catalysts, olefin polymerization, resting states
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ISO 690PANCHENKO, Valentina N., Dmitrii E. BABUSHKIN, Hans-Herbert BRINTZINGER, 2015. Zirconium-Allyl Complexes as Resting States in Zirconocene-Catalyzed α-Olefin Polymerization. In: Macromolecular Rapid Communications. 2015, 36(2), pp. 249-253. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.201400444
BibTex
@article{Panchenko2015Zirco-29331,
  year={2015},
  doi={10.1002/marc.201400444},
  title={Zirconium-Allyl Complexes as Resting States in Zirconocene-Catalyzed α-Olefin Polymerization},
  number={2},
  volume={36},
  issn={1022-1336},
  journal={Macromolecular Rapid Communications},
  pages={249--253},
  author={Panchenko, Valentina N. and Babushkin, Dmitrii E. and Brintzinger, Hans-Herbert}
}
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