Reactions of Benzylidene(pentacarbonyl) Complexes

Fischer, Helmut; Zeuner, Siegfried; Schmid, Johann; Hofmann, Josef

Reactions of Benzylidene(pentacarbonyl) Complexes

Dateien

Zu diesem Dokument gibt es keine Dateien.

Datum

1989

Autor:innen

Fischer, Helmut

Zeuner, Siegfried

Schmid, Johann

Hofmann, Josef

Publikationstyp

Beitrag zu einem Konferenzband

Publikationsstatus

Published

Erschienen in

SCHUBERT, U., ed.. Advances in Metal Carbene Chemistry. Dordrecht: Springer Netherlands, 1989, pp. 185-188. ISBN 978-94-010-7541-1. Available under: doi: 10.1007/978-94-009-2317-1_23

Zusammenfassung

Benzylidene(pentacarbonyl) complexes of chromium, molybdenum, and tungsten can be prepared from pentacarbonyl[alpha-alkoxybenzyl] metal-lates by alkoxide abstraction with tetrafluoroboric acid. The extreme electrophilicity of their benzylidene carbon atoms dominates their reactivities. They react readily, even at low temperatures, with a large number of nucleophiles (phosphines, ethers, thioethers, carbon monoxide, alkenes, conjugated diolefines, and alkynes), giving coupling products, both those eliminated from the metal and those still coordinated.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

FISCHER, Helmut, Siegfried ZEUNER, Johann SCHMID, Josef HOFMANN, 1989. Reactions of Benzylidene(pentacarbonyl) Complexes. In: SCHUBERT, U., ed.. Advances in Metal Carbene Chemistry. Dordrecht: Springer Netherlands, 1989, pp. 185-188. ISBN 978-94-010-7541-1. Available under: doi: 10.1007/978-94-009-2317-1_23

BibTex

@inproceedings{Fischer1989React-23576,
  year={1989},
  doi={10.1007/978-94-009-2317-1_23},
  title={Reactions of Benzylidene(pentacarbonyl) Complexes},
  isbn={978-94-010-7541-1},
  publisher={Springer Netherlands},
  address={Dordrecht},
  booktitle={Advances in Metal Carbene Chemistry},
  pages={185--188},
  editor={Schubert, U.},
  author={Fischer, Helmut and Zeuner, Siegfried and Schmid, Johann and Hofmann, Josef}
}

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