Dynamic and Fluorescent Nanoscale Phenanthroline/Terpyridine Zinc(II) Ladders : Self-Recognition in Unlike Ligand/Like Metal Coordination Scenarios

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2005
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Schmittel, Michael
Kalsani, Venkateshwarlu
Kishore, Ravuri S. K.
Bats, Jan W.
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Journal of the American Chemical Society. 2005, 127(33), pp. 11544-11545. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja0525096
Zusammenfassung

A new coordination kit, the HETTAP approach, is described, which allows one to prepare supramolecular heteroleptic metal phenanthroline/terpyridine racks and ladders in basically quantitative yield. Due to the dynamic nature of the nanoladder structures, a two-step double-transmetalation and scenarios with like metal/unlike ligand recognition were realized.

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ISO 690SCHMITTEL, Michael, Venkateshwarlu KALSANI, Ravuri S. K. KISHORE, Helmut CÖLFEN, Jan W. BATS, 2005. Dynamic and Fluorescent Nanoscale Phenanthroline/Terpyridine Zinc(II) Ladders : Self-Recognition in Unlike Ligand/Like Metal Coordination Scenarios. In: Journal of the American Chemical Society. 2005, 127(33), pp. 11544-11545. ISSN 0002-7863. eISSN 1520-5126. Available under: doi: 10.1021/ja0525096
BibTex
@article{Schmittel2005-08Dynam-40395,
  year={2005},
  doi={10.1021/ja0525096},
  title={Dynamic and Fluorescent Nanoscale Phenanthroline/Terpyridine Zinc(II) Ladders : Self-Recognition in Unlike Ligand/Like Metal Coordination Scenarios},
  number={33},
  volume={127},
  issn={0002-7863},
  journal={Journal of the American Chemical Society},
  pages={11544--11545},
  author={Schmittel, Michael and Kalsani, Venkateshwarlu and Kishore, Ravuri S. K. and Cölfen, Helmut and Bats, Jan W.}
}
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