Evidence for a structurally-driven insulator-to-metal transition in VO2 : a view from the ultrafast timescale
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We apply ultrafast spectroscopy to establish a time-domain hierarchy between structural and electronic effects in a strongly correlated electron system. We discuss the case of the model system VO2 , a prototypical nonmagnetic compound that exhibits cell doubling, charge localization, and a metal-insulator transition below 340 K. We initiate the formation of the metallic phase by prompt hole photo-doping into the valence band of the low- T insulator. The insulator-to-metal transition is, however, delayed with respect to hole injection, exhibiting a bottleneck time scale, associated with the phonon connecting the two crystallographic phases. This structural bottleneck is observed despite faster depletion of the d bands and is indicative of important bandlike character for this controversial insulator.
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CAVALLERI, Andrea, Thomas DEKORSY, Henry H. W. CHONG, Jean-Claude KIEFFER, Robert W. SCHOENLEIN, 2004. Evidence for a structurally-driven insulator-to-metal transition in VO2 : a view from the ultrafast timescale. In: Physical Review B. 2004, 70(16), 161102. Available under: doi: 10.1103/PhysRevB.70.161102BibTex
@article{Cavalleri2004Evide-5099, year={2004}, doi={10.1103/PhysRevB.70.161102}, title={Evidence for a structurally-driven insulator-to-metal transition in VO2 : a view from the ultrafast timescale}, number={16}, volume={70}, journal={Physical Review B}, author={Cavalleri, Andrea and Dekorsy, Thomas and Chong, Henry H. W. and Kieffer, Jean-Claude and Schoenlein, Robert W.}, note={Article Number: 161102} }
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