A simple strategy for the synthesis of well-defined bassanite nanorods

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2015
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Zusammenfassung

Bassanite is a metastable but industrially important form of calcium sulfate, which is commonly produced by heating of gypsum. Here we show that pure bassanite can also be obtained at ambient conditions by quenching aqueous CaSO4 solutions in ethanol. This highlights that organic solvents can actually induce the formation of metastable phases rather than freezing precipitation processes.

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540 Chemie
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CALCIUM-SULFATE HEMIHYDRATE; GYPSUM; CRYSTALLIZATION; PRECIPITATION; DIHYDRATE; WATER; TRANSFORMATION; METHANOL; GROWTH; PHASE
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ISO 690TRITSCHLER, Ulrich, Matthias KELLERMEIER, Christian DEBUS, Andreas KEMPTER, Helmut CÖLFEN, 2015. A simple strategy for the synthesis of well-defined bassanite nanorods. In: CrystEngComm. 2015, 17(20), pp. 3772-3776. eISSN 1466-8033. Available under: doi: 10.1039/C5CE00519A
BibTex
@article{Tritschler2015simpl-31092,
  year={2015},
  doi={10.1039/C5CE00519A},
  title={A simple strategy for the synthesis of well-defined bassanite nanorods},
  number={20},
  volume={17},
  journal={CrystEngComm},
  pages={3772--3776},
  author={Tritschler, Ulrich and Kellermeier, Matthias and Debus, Christian and Kempter, Andreas and Cölfen, Helmut}
}
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