Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine

Fischer, Helmut; Treier, Kornelia; Troll, Carsten; Stumpf, Rüdiger

Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine

Dateien

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Datum

1995

Autor:innen

Fischer, Helmut

Treier, Kornelia

Troll, Carsten

Stumpf, Rüdiger

Publikationstyp

Zeitschriftenartikel

Publikationsstatus

Published

Erschienen in

Journal of the Chemical Society, Chemical Communications. 1995(23), pp. 2461-2463. ISSN 0022-4936. Available under: doi: 10.1039/C39950002461

Zusammenfassung

Pentacarbonyltungsten-coordinated selenobenzaldehydes, (CO)5W[Se[double bond, length half m-dash]C(C6H4R-p)H](R = QMe, H, CF3), react with ButS–C[triple bond, length half m-dash]C–SBut by addition of the C[triple bond, length half m-dash]C to the Se[double bond, length half m-dash]C bond to give 2H-selenete complexes; treatment of the selenete complex (R[double bond, length half m-dash]H) with NEt4Br affords the uncoordinated 2H-selenete and a 3,4-dihydro-1,2-diselenine.

Fachgebiet (DDC)

540 Chemie

Zitieren

ISO 690

FISCHER, Helmut, Kornelia TREIER, Carsten TROLL, Rüdiger STUMPF, 1995. Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine. In: Journal of the Chemical Society, Chemical Communications. 1995(23), pp. 2461-2463. ISSN 0022-4936. Available under: doi: 10.1039/C39950002461

BibTex

@article{Fischer1995Synth-23175,
  year={1995},
  doi={10.1039/C39950002461},
  title={Synthesis of the first 2H-selenete complexes, decomplexation and dimerization to dihydro-1,2-diselenine},
  number={23},
  issn={0022-4936},
  journal={Journal of the Chemical Society, Chemical Communications},
  pages={2461--2463},
  author={Fischer, Helmut and Treier, Kornelia and Troll, Carsten and Stumpf, Rüdiger}
}

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