Publikation: Four different emissions from a Pt(Bodipy)(PEt3)2(S-Pyrene) dyad
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Dalton Transactions. 2019, 48(4), pp. 1171-1174. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/C8DT04823A
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The Pt(bodipy)-(mercaptopyrene) dyad BPtSPyr shows four different emissions: intense near-infrared phosphorescence (Φph up to 15%) from a charge-transfer state pyrS˙+-Pt-BDP˙−, additional fluorescence and phosphorescence emissions from the 1ππ* and 3ππ* states of the bodipy ligand at r.t., and phosphorescence from the pyrene 3ππ* and the bodipy 3ππ* states in a glassy matrix at 77 K.
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IRMLER, Peter, Franciska S. GOGESCH, Christopher B. LARSEN, Oliver S. WENGER, Rainer F. WINTER, 2019. Four different emissions from a Pt(Bodipy)(PEt3)2(S-Pyrene) dyad. In: Dalton Transactions. 2019, 48(4), pp. 1171-1174. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/C8DT04823ABibTex
@article{Irmler2019-01-22diffe-44418,
year={2019},
doi={10.1039/C8DT04823A},
title={Four different emissions from a Pt(Bodipy)(PEt<sub>3</sub>)<sub>2</sub>(S-Pyrene) dyad},
number={4},
volume={48},
issn={1477-9226},
journal={Dalton Transactions},
pages={1171--1174},
author={Irmler, Peter and Gogesch, Franciska S. and Larsen, Christopher B. and Wenger, Oliver S. and Winter, Rainer F.}
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<dcterms:abstract xml:lang="eng">The Pt(bodipy)-(mercaptopyrene) dyad BPtSPyr shows four different emissions: intense near-infrared phosphorescence (Φ<sub>ph</sub> up to 15%) from a charge-transfer state pyrS˙<sup>+</sup>-Pt-BDP˙<sup>−</sup>, additional fluorescence and phosphorescence emissions from the <sup>1</sup>ππ* and <sup>3</sup>ππ* states of the bodipy ligand at r.t., and phosphorescence from the pyrene <sup>3</sup>ππ* and the bodipy <sup>3</sup>ππ* states in a glassy matrix at 77 K.</dcterms:abstract>
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