Ynol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactions

Kurzanzeige
dc.contributor.authorWender, Paul A.
dc.contributor.authorEbner, Christian
dc.contributor.authorFennell, Brandon D.
dc.contributor.authorInagaki, Fuyuhiko
dc.contributor.authorSchröder, Birte
dc.date.accessioned2017-12-12T10:29:56Z
dc.date.available2017-12-12T10:29:56Z
dc.date.issued2017-11-03eng
dc.description.abstractThe previously unexplored metal-catalyzed [5 + 2] cycloadditions of vinylcyclopropanes (VCPs) and electron-rich alkynes (ynol ethers) have been found to provide a highly efficient, direct route to dioxygenated seven-membered rings, a common feature of numerous natural and non-natural targets and building blocks for synthesis. The reactions proceed in high yield at room temperature and tolerate a broad range of functionalities. Substituted VCPs were found to react with high regioselectivity.eng
dc.description.versionpublishedeng
dc.identifier.doi10.1021/acs.orglett.7b02765eng
dc.identifier.pmid29034684eng
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/40897
dc.language.isoengeng
dc.subject.ddc540eng
dc.titleYnol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactionseng
dc.typeJOURNAL_ARTICLEeng
dspace.entity.typePublication
kops.citation.bibtex
@article{Wender2017-11-03Ether-40897,
  year={2017},
  doi={10.1021/acs.orglett.7b02765},
  title={Ynol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactions},
  number={21},
  volume={19},
  issn={1523-7060},
  journal={Organic Letters},
  pages={5810--5813},
  author={Wender, Paul A. and Ebner, Christian and Fennell, Brandon D. and Inagaki, Fuyuhiko and Schröder, Birte}
}
kops.citation.iso690WENDER, Paul A., Christian EBNER, Brandon D. FENNELL, Fuyuhiko INAGAKI, Birte SCHRÖDER, 2017. Ynol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactions. In: Organic Letters. 2017, 19(21), pp. 5810-5813. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/acs.orglett.7b02765deu
kops.citation.iso690WENDER, Paul A., Christian EBNER, Brandon D. FENNELL, Fuyuhiko INAGAKI, Birte SCHRÖDER, 2017. Ynol Ethers as Ketene Equivalents in Rhodium-Catalyzed Intermolecular [5 + 2] Cycloaddition Reactions. In: Organic Letters. 2017, 19(21), pp. 5810-5813. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/acs.orglett.7b02765eng
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kops.sourcefieldOrganic Letters. 2017, <b>19</b>(21), pp. 5810-5813. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/acs.orglett.7b02765deu
kops.sourcefield.plainOrganic Letters. 2017, 19(21), pp. 5810-5813. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/acs.orglett.7b02765deu
kops.sourcefield.plainOrganic Letters. 2017, 19(21), pp. 5810-5813. ISSN 1523-7060. eISSN 1523-7052. Available under: doi: 10.1021/acs.orglett.7b02765eng
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source.identifier.eissn1523-7052eng
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source.periodicalTitleOrganic Letterseng

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