Publikation: Nucleation and growth of thermoreversible polymer gels
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2013
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Physical Review E. 2013, 87(1), 012308. ISSN 1539-3755. eISSN 1550-2376. Available under: doi: 10.1103/PhysRevE.87.012308
Zusammenfassung
We study the spatiotemporal low-frequency microrheology of a gelatin gel during the sol-gel transition after a fast temperature quench by tracking the motion of embedded colloidal particles. From the particle dynamics two different mechanisms responsible for the gelation of the sol phase can be identified: a fast process associated to the local nucleation of triple helices and a slow fiber growth triggered by presence of an intact network. We associate the latter to a gelation front propagating into the sol phase whose speed depends linearly on the quench depth and which accelerates the local rate of the sol-gel transition.
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GOMEZ-SOLANO, Juan Ruben, Valentin BLICKLE, Clemens BECHINGER, 2013. Nucleation and growth of thermoreversible polymer gels. In: Physical Review E. 2013, 87(1), 012308. ISSN 1539-3755. eISSN 1550-2376. Available under: doi: 10.1103/PhysRevE.87.012308BibTex
@article{GomezSolano2013-01-14Nucle-39284,
year={2013},
doi={10.1103/PhysRevE.87.012308},
title={Nucleation and growth of thermoreversible polymer gels},
number={1},
volume={87},
issn={1539-3755},
journal={Physical Review E},
author={Gomez-Solano, Juan Ruben and Blickle, Valentin and Bechinger, Clemens},
note={Article Number: 012308}
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