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Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems

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2014

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Kowalski, Konrad
Szczupak, Lukasz
Skiba, Joanna
Czerwieniec, Rafal
Therrien, Bruno

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https://doi.org/10.1021/om401191q
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Organometallics. 2014, 33(18), pp. 4697-4705. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om401191q

Zusammenfassung

The synthesis of two new donor–acceptor ferrocenyl derivatives with Meldrum’s acid based nonplanar acceptor substituents is presented. Both compounds are obtained in high yields in a simple reaction protocol under mild conditions using either 1-acetyl- or 1,1′-diacetylferrocene and Meldrum’s acid. Both products have been characterized spectroscopically, by single-crystal X-ray structure analysis, by electrochemical and UV/vis/IR spectroelectrochemical measurements, and by (TD)-DFT calculations. The spectroelectrochemical measurements disclose that the 2,2-dimethyl-1,3-dioxane-4,6-dione moiety is a moderately strong electron acceptor.

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ISO 690KOWALSKI, Konrad, Lukasz SZCZUPAK, Joanna SKIBA, Obadah S. ABDEL-RAHMAN, Rainer F. WINTER, Rafal CZERWIENIEC, Bruno THERRIEN, 2014. Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems. In: Organometallics. 2014, 33(18), pp. 4697-4705. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om401191q
BibTex
@article{Kowalski2014Synth-29102,
  year={2014},
  doi={10.1021/om401191q},
  title={Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems},
  number={18},
  volume={33},
  issn={0276-7333},
  journal={Organometallics},
  pages={4697--4705},
  author={Kowalski, Konrad and Szczupak, Lukasz and Skiba, Joanna and Abdel-Rahman, Obadah S. and Winter, Rainer F. and Czerwieniec, Rafal and Therrien, Bruno}
}
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