Publikation: Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems
Lade...
Dateien
Zu diesem Dokument gibt es keine Dateien.
Datum
2014
Autor:innen
Kowalski, Konrad
Szczupak, Lukasz
Skiba, Joanna
Czerwieniec, Rafal
Therrien, Bruno
Herausgeber:innen
Kontakt
ISSN der Zeitschrift
item.preview.dc.identifier.eissn
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
item.preview.dc.identifier.arxiv
Internationale Patentnummer
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Organometallics. 2014, 33(18), pp. 4697-4705. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om401191q
Zusammenfassung
The synthesis of two new donor–acceptor ferrocenyl derivatives with Meldrum’s acid based nonplanar acceptor substituents is presented. Both compounds are obtained in high yields in a simple reaction protocol under mild conditions using either 1-acetyl- or 1,1′-diacetylferrocene and Meldrum’s acid. Both products have been characterized spectroscopically, by single-crystal X-ray structure analysis, by electrochemical and UV/vis/IR spectroelectrochemical measurements, and by (TD)-DFT calculations. The spectroelectrochemical measurements disclose that the 2,2-dimethyl-1,3-dioxane-4,6-dione moiety is a moderately strong electron acceptor.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
KOWALSKI, Konrad, Lukasz SZCZUPAK, Joanna SKIBA, Obadah S. ABDEL-RAHMAN, Rainer F. WINTER, Rafal CZERWIENIEC, Bruno THERRIEN, 2014. Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems. In: Organometallics. 2014, 33(18), pp. 4697-4705. ISSN 0276-7333. eISSN 1520-6041. Available under: doi: 10.1021/om401191qBibTex
@article{Kowalski2014Synth-29102,
year={2014},
doi={10.1021/om401191q},
title={Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems},
number={18},
volume={33},
issn={0276-7333},
journal={Organometallics},
pages={4697--4705},
author={Kowalski, Konrad and Szczupak, Lukasz and Skiba, Joanna and Abdel-Rahman, Obadah S. and Winter, Rainer F. and Czerwieniec, Rafal and Therrien, Bruno}
}RDF
<rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29102">
<dc:creator>Kowalski, Konrad</dc:creator>
<dc:contributor>Kowalski, Konrad</dc:contributor>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/29102"/>
<dc:contributor>Czerwieniec, Rafal</dc:contributor>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dc:creator>Skiba, Joanna</dc:creator>
<dc:contributor>Szczupak, Lukasz</dc:contributor>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dc:contributor>Skiba, Joanna</dc:contributor>
<dc:creator>Therrien, Bruno</dc:creator>
<dc:contributor>Abdel-Rahman, Obadah S.</dc:contributor>
<dc:language>eng</dc:language>
<dc:creator>Czerwieniec, Rafal</dc:creator>
<dc:creator>Abdel-Rahman, Obadah S.</dc:creator>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-10-13T08:45:27Z</dc:date>
<dc:creator>Winter, Rainer F.</dc:creator>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dc:contributor>Therrien, Bruno</dc:contributor>
<dcterms:title>Synthesis, Structure, and Spectroelectrochemistry of Ferrocenyl–Meldrum’s Acid Donor–Acceptor Systems</dcterms:title>
<dc:creator>Szczupak, Lukasz</dc:creator>
<dcterms:issued>2014</dcterms:issued>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dc:contributor>Winter, Rainer F.</dc:contributor>
<dcterms:abstract xml:lang="eng">The synthesis of two new donor–acceptor ferrocenyl derivatives with Meldrum’s acid based nonplanar acceptor substituents is presented. Both compounds are obtained in high yields in a simple reaction protocol under mild conditions using either 1-acetyl- or 1,1′-diacetylferrocene and Meldrum’s acid. Both products have been characterized spectroscopically, by single-crystal X-ray structure analysis, by electrochemical and UV/vis/IR spectroelectrochemical measurements, and by (TD)-DFT calculations. The spectroelectrochemical measurements disclose that the 2,2-dimethyl-1,3-dioxane-4,6-dione moiety is a moderately strong electron acceptor.</dcterms:abstract>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2014-10-13T08:45:27Z</dcterms:available>
</rdf:Description>
</rdf:RDF>Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Kontakt
URL der Originalveröffentl.
Prüfdatum der URL
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
