Publikation: Multilayered CaCO3/block-copolymer materials via amorphous precursor to crystal transformation
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2010
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Colloids and Surfaces A : Physicochemical and Engineering Aspects. 2010, 354(1-3), pp. 279-283. ISSN 0927-7757. eISSN 1873-4359
Zusammenfassung
Nacre-type organic/inorganic hybrid multilayers can be fabricated through a continuous polymer-induced liquid precursor (PILP) layer formed underneath a poly(styrene)-block-poly(acrylic acid) (PS-b-PAA) block copolymer monolayer. Subsequent Layer-by-Layer transfer of block copolymer/PILP films leads to a multilayer with organic inorganic hybrid architecture. The subsequent annealing process transforms the PILP layers into layers of polycrystalline CaCO3, which morphologically resemble that of biogenic nacre.
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Fachgebiet (DDC)
540 Chemie
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Nacre, Thin films, Calcium carbonate, Block copolymer, Monolayers
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GONG, Haofei, Manuela PLUNTKE, Othmar MARTI, Paul WALTHER, Laurie GOWER, Helmut CÖLFEN, Dirk VOLKMER, 2010. Multilayered CaCO3/block-copolymer materials via amorphous precursor to crystal transformation. In: Colloids and Surfaces A : Physicochemical and Engineering Aspects. 2010, 354(1-3), pp. 279-283. ISSN 0927-7757. eISSN 1873-4359BibTex
@article{Gong2010Multi-9891, year={2010}, title={Multilayered CaCO3/block-copolymer materials via amorphous precursor to crystal transformation}, number={1-3}, volume={354}, issn={0927-7757}, journal={Colloids and Surfaces A : Physicochemical and Engineering Aspects}, pages={279--283}, author={Gong, Haofei and Pluntke, Manuela and Marti, Othmar and Walther, Paul and Gower, Laurie and Cölfen, Helmut and Volkmer, Dirk} }
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