Publikation:

Efficient Suppression of Chain Transfer and Branching via Cs-Type Shielding in a Neutral Ni(II) Catalyst

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2021

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Wang, Chaoqun
Kang, Xiaohui
Dai, Shengyu
Cui, Fengchao
Li, Yunqi
Mu, Hongliang

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Angewandte Chemie International Edition. Wiley. 2021, 60(8), pp. 4018-4022. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.202013069

Zusammenfassung

An effective shielding of both apical positions of a neutral Ni(II) active site is achieved by dibenzosuberyl groups, both attached via the same donors' N -aryl group in a C s -type arrangement. The key aniline building block is accessible in a single step from commercially available dibenzosuberol. This shielding approach suppresses chain transfer and branch formation to such an extent that ultrahigh molecular weight polyethylenes (5 × 10 6 g mol -1 ) are accessible, with a strictly linear microstructure (< 0.1 branches/1000C). Key features of this highly active (4.3 × 10 5 turnovers h -1 ) catalyst are an exceptionally facile preparation, thermal robustness (up to 90 o C polymerization temperature), ability for living polymerization and compatibility with THF as a polar reaction medium.

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540 Chemie

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coordination polymerization, Cs shielding, homogeneous catalysis, linear UHMWPE, nickel catalyst

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ISO 690WANG, Chaoqun, Xiaohui KANG, Shengyu DAI, Fengchao CUI, Yunqi LI, Hongliang MU, Stefan MECKING, Zhongbao JIAN, 2021. Efficient Suppression of Chain Transfer and Branching via Cs-Type Shielding in a Neutral Ni(II) Catalyst. In: Angewandte Chemie International Edition. Wiley. 2021, 60(8), pp. 4018-4022. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.202013069
BibTex
@article{Wang2021-02-19Effic-51877,
  year={2021},
  doi={10.1002/anie.202013069},
  title={Efficient Suppression of Chain Transfer and Branching via Cs-Type Shielding in a Neutral Ni(II) Catalyst},
  number={8},
  volume={60},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={4018--4022},
  author={Wang, Chaoqun and Kang, Xiaohui and Dai, Shengyu and Cui, Fengchao and Li, Yunqi and Mu, Hongliang and Mecking, Stefan and Jian, Zhongbao}
}
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