Publikation: Polymer-Controlled Biomimetic Mineralization of Novel Inorganic Materials
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Biomineralization processes result in organic-inorganic hybrid materials with complex shape, hierarchical organization, and superior materials properties. Chemistry, which is inspired by these processes, aims to mimic biomineralization principles and to transfer them to the general control of crystallization processes using an environmentally benign route. Recent progress in the field has revealed that polymer controlled crystallization often does not follow the classical textbook view of ion-mediated crystallization but instead is based on nanoparticles as building units. In this chapter, the latest advances in hydrophilic polymer-controlled crystallization are summarized with focus on structures with functionality, i.e., special mechanical or optical properties. Size, shape, phase, dimension, assembly, etc. have significant relevance for the properties of semiconductor nanocrystals, metal nanostructures, or on the magnetism and spectral characteristics of oxides and other inorganic materials. The resulting unique hierarchical materials with structural speciality and complexity and a size range spanning from nanometers to micrometers are expected to be interesting in various fields of applications, such as catalysis, medicine, electronics, ceramics, pigments, and cosmetics.
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CÖLFEN, Helmut, Markus ANTONIETTI, 2010. Polymer-Controlled Biomimetic Mineralization of Novel Inorganic Materials. In: SIGEL, Astrid, ed., Helmut SIGEL, ed., Roland K. O. SIGEL, ed.. Biomineralization : From Nature to Application. Chichester, UK: John Wiley & Sons, Ltd, 2010, pp. 607-643. ISBN 978-0-470-03525-2. Available under: doi: 10.1002/9780470986325.ch18BibTex
@incollection{Colfen2010Polym-40367, year={2010}, doi={10.1002/9780470986325.ch18}, title={Polymer-Controlled Biomimetic Mineralization of Novel Inorganic Materials}, isbn={978-0-470-03525-2}, publisher={John Wiley & Sons, Ltd}, address={Chichester, UK}, booktitle={Biomineralization : From Nature to Application}, pages={607--643}, editor={Sigel, Astrid and Sigel, Helmut and Sigel, Roland K. O.}, author={Cölfen, Helmut and Antonietti, Markus} }
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