Publikation: Polymer Dispersions from Catalytic Polymerization in Aqueous Systems
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2007
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Colloid and Polymer Science. 2007, 285(6), pp. 605-619. ISSN 0303-402X. eISSN 1435-1536. Available under: doi: 10.1007/s00396-006-1587-3
Zusammenfassung
By contrast to traditional free radical emulsion polymerization, catalytic polymerization allows for polymer microstructure control. In terms of polymerizable monomers, both techniques are largely complementary. Since the beginning of this decade, an increasing number of reports on polyolefin, polybutadiene, polyalkenamer, polynorbornene, polyketone, and polyacetylene dispersions prepared by catalytic polymerization in disperse aqueous systems has appeared. This contribution reviews the preparation of these dispersions, their colloidal properties, particle formation mechanisms, particle morphologies, and polymer microstructures.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
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Catalytic polymerization, Controlled polymerization, Stereoregular, Polyolefin latex, Polyketone latex, Polynorbornene latex
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MECKING, Stefan, 2007. Polymer Dispersions from Catalytic Polymerization in Aqueous Systems. In: Colloid and Polymer Science. 2007, 285(6), pp. 605-619. ISSN 0303-402X. eISSN 1435-1536. Available under: doi: 10.1007/s00396-006-1587-3BibTex
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year={2007},
doi={10.1007/s00396-006-1587-3},
title={Polymer Dispersions from Catalytic Polymerization in Aqueous Systems},
number={6},
volume={285},
issn={0303-402X},
journal={Colloid and Polymer Science},
pages={605--619},
author={Mecking, Stefan}
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<dcterms:abstract xml:lang="eng">By contrast to traditional free radical emulsion polymerization, catalytic polymerization allows for polymer microstructure control. In terms of polymerizable monomers, both techniques are largely complementary. Since the beginning of this decade, an increasing number of reports on polyolefin, polybutadiene, polyalkenamer, polynorbornene, polyketone, and polyacetylene dispersions prepared by catalytic polymerization in disperse aqueous systems has appeared. This contribution reviews the preparation of these dispersions, their colloidal properties, particle formation mechanisms, particle morphologies, and polymer microstructures.</dcterms:abstract>
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