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The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand

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Huttner_239138.pdf
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1978

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Huttner, Gottfried
Bell, Larry G.
Friedrich, Peter
Bejenke, Vera
Neugebauer, Dietmar

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http://nbn-resolving.de/urn:nbn:de:bsz:352-239138
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https://doi.org/10.1016/S0022-328X(00)81301-7
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Published

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Journal of Organometallic Chemistry. 1978, 145(3), pp. 329-333. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)81301-7

Zusammenfassung

The crystal and molecular structure of the complex (C5H5)2W(CO)2 has been determined by X-ray analysis R1 = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided.

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540 Chemie

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ISO 690HUTTNER, Gottfried, Hans-Herbert BRINTZINGER, Larry G. BELL, Peter FRIEDRICH, Vera BEJENKE, Dietmar NEUGEBAUER, 1978. The structure of (C5H5)2 W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand. In: Journal of Organometallic Chemistry. 1978, 145(3), pp. 329-333. ISSN 0022-328X. Available under: doi: 10.1016/S0022-328X(00)81301-7
BibTex
@article{Huttner1978struc-23913,
  year={1978},
  doi={10.1016/S0022-328X(00)81301-7},
  title={The structure of (C<sub>5</sub>H<sub>5</sub>)<sub>2</sub> W(CO)<sub>2</sub> a compound containing a bent trihapto-cyclopentadienyl ligand},
  number={3},
  volume={145},
  issn={0022-328X},
  journal={Journal of Organometallic Chemistry},
  pages={329--333},
  author={Huttner, Gottfried and Brintzinger, Hans-Herbert and Bell, Larry G. and Friedrich, Peter and Bejenke, Vera and Neugebauer, Dietmar}
}
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    <dcterms:title>The structure of (C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt; W(CO)&lt;sub&gt;2&lt;/sub&gt; a compound containing a bent trihapto-cyclopentadienyl ligand</dcterms:title>
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    <dcterms:abstract xml:lang="eng">The crystal and molecular structure of the complex (C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;W(CO)&lt;sub&gt;2&lt;/sub&gt; has been determined by X-ray analysis R&lt;sub&gt;1&lt;/sub&gt; = 0.063). The structure contains a trihapto-cyclopentadienyl ligand, bent along its 1,3-axis by 20°. By this unusual structure, a 20-electron valence configuration of the central metal is avoided.</dcterms:abstract>
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