Publikation:

Ultrafast X-Ray Solution Scattering Reveals an Unknown Reaction Intermediate in the Photolysis of [Ru3(CO)12]

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2008

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Kong, Qingyu
Lee, Jae Hyuk
Wulff, Michael
Ihee, Hyotcherl
Koch, Michel H. J.

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https://doi.org/10.1002/anie.200801153
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Angewandte Chemie International Edition. Wiley. 2008, 47(30), pp. 5550-5553. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200801153

Zusammenfassung

A matter of technique: Time-resolved X-ray scattering was used to probe the photolysis of [Ru3(CO)12] in cyclohexane, and a new intermediate was identified besides the two μ-CO intermediates known from ultrafast IR spectroscopy (see scheme). The major and hitherto undetected intermediate contains only terminal CO and thus escaped detection by IR spectroscopy based on absorption bands of bridging CO.

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ISO 690KONG, Qingyu, Jae Hyuk LEE, Anton PLECH, Michael WULFF, Hyotcherl IHEE, Michel H. J. KOCH, 2008. Ultrafast X-Ray Solution Scattering Reveals an Unknown Reaction Intermediate in the Photolysis of [Ru3(CO)12]. In: Angewandte Chemie International Edition. Wiley. 2008, 47(30), pp. 5550-5553. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200801153
BibTex
@article{Kong2008Ultra-58691,
  year={2008},
  doi={10.1002/anie.200801153},
  title={Ultrafast X-Ray Solution Scattering Reveals an Unknown Reaction Intermediate in the Photolysis of [Ru<sub>3</sub>(CO)<sub>12</sub>]},
  number={30},
  volume={47},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={5550--5553},
  author={Kong, Qingyu and Lee, Jae Hyuk and Plech, Anton and Wulff, Michael and Ihee, Hyotcherl and Koch, Michel H. J.}
}
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