Exposure of [MnIII6CrIII]3+ single-molecule magnets to soft X-rays : the effect of the counterions on radiation stability

Kurzanzeige
dc.contributor.authorHelmstedt, Andreasdeu
dc.contributor.authorSacher, Marc D.deu
dc.contributor.authorGryzia, Aarondeu
dc.contributor.authorHarder, Alexanderdeu
dc.contributor.authorBrechling, Armindeu
dc.contributor.authorMüller, Norbertdeu
dc.contributor.authorHeinzmann, Ulrichdeu
dc.contributor.authorHoeke, Veronikadeu
dc.contributor.authorKrickemeyer, Erichdeu
dc.contributor.authorGlaser, Thorstendeu
dc.contributor.authorBouvron, Samuel
dc.contributor.authorFonin, Mikhail
dc.date.accessioned2012-03-20T07:44:56Zdeu
dc.date.available2012-03-20T07:44:56Zdeu
dc.date.issued2012
dc.description.abstractX-ray absorption spectroscopy studies of the [MnIII6CrIII]3+ single-molecule magnet deposited as a microcrystalline layer on gold substrates are presented. The oxidation state of the manganese centers changes from MnIII to MnII due to irradiation with soft X-rays. The influence of the charge-neutralizing anions on the stability of [MnIII6CrIII]3+ against soft X-ray exposure is investigated for the different anions tetraphenylborate (BPh4−), lactate (C3H5O3−) and perchlorate (ClO4−). The exposure dependence of the radiation-induced reduction process is compared for [MnIII6CrIII]3+ with the three different anions.eng
dc.description.versionpublished
dc.identifier.citationFirst publ. in: Journal of Electron Spectroscopy and Related Phenomena ; 184 (2012), 11/12. - S. 583-588deu
dc.identifier.doi10.1016/j.elspec.2011.11.002deu
dc.identifier.ppn362143536deu
dc.identifier.urihttp://kops.uni-konstanz.de/handle/123456789/18020
dc.language.isoengdeu
dc.legacy.dateIssued2012-03-20deu
dc.rightsterms-of-usedeu
dc.rights.urihttps://rightsstatements.org/page/InC/1.0/deu
dc.subjectXASdeu
dc.subjectabsorption spectroscopydeu
dc.subjectreductiondeu
dc.subjectManganesedeu
dc.subjectsingle-molecule magnetdeu
dc.subjectSMMdeu
dc.subject.ddc530deu
dc.titleExposure of [MnIII6CrIII]3+ single-molecule magnets to soft X-rays : the effect of the counterions on radiation stabilityeng
dc.typeJOURNAL_ARTICLEdeu
dspace.entity.typePublication
kops.citation.bibtex
@article{Helmstedt2012Expos-18020,
  year={2012},
  doi={10.1016/j.elspec.2011.11.002},
  title={Exposure of [MnIII6CrIII]3+ single-molecule magnets to soft X-rays : the effect of the counterions on radiation stability},
  number={11-12},
  volume={184},
  issn={0368-2048},
  journal={Journal of Electron Spectroscopy and Related Phenomena},
  pages={583--588},
  author={Helmstedt, Andreas and Sacher, Marc D. and Gryzia, Aaron and Harder, Alexander and Brechling, Armin and Müller, Norbert and Heinzmann, Ulrich and Hoeke, Veronika and Krickemeyer, Erich and Glaser, Thorsten and Bouvron, Samuel and Fonin, Mikhail}
}
kops.citation.iso690HELMSTEDT, Andreas, Marc D. SACHER, Aaron GRYZIA, Alexander HARDER, Armin BRECHLING, Norbert MÜLLER, Ulrich HEINZMANN, Veronika HOEKE, Erich KRICKEMEYER, Thorsten GLASER, Samuel BOUVRON, Mikhail FONIN, 2012. Exposure of [MnIII6CrIII]3+ single-molecule magnets to soft X-rays : the effect of the counterions on radiation stability. In: Journal of Electron Spectroscopy and Related Phenomena. 2012, 184(11-12), pp. 583-588. ISSN 0368-2048. Available under: doi: 10.1016/j.elspec.2011.11.002deu
kops.citation.iso690HELMSTEDT, Andreas, Marc D. SACHER, Aaron GRYZIA, Alexander HARDER, Armin BRECHLING, Norbert MÜLLER, Ulrich HEINZMANN, Veronika HOEKE, Erich KRICKEMEYER, Thorsten GLASER, Samuel BOUVRON, Mikhail FONIN, 2012. Exposure of [MnIII6CrIII]3+ single-molecule magnets to soft X-rays : the effect of the counterions on radiation stability. In: Journal of Electron Spectroscopy and Related Phenomena. 2012, 184(11-12), pp. 583-588. ISSN 0368-2048. Available under: doi: 10.1016/j.elspec.2011.11.002eng
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kops.sourcefieldJournal of Electron Spectroscopy and Related Phenomena. 2012, <b>184</b>(11-12), pp. 583-588. ISSN 0368-2048. Available under: doi: 10.1016/j.elspec.2011.11.002deu
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kops.sourcefield.plainJournal of Electron Spectroscopy and Related Phenomena. 2012, 184(11-12), pp. 583-588. ISSN 0368-2048. Available under: doi: 10.1016/j.elspec.2011.11.002eng
kops.submitter.emailoleg.kozlov@uni-konstanz.dedeu
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