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Control over the Structure of Ice and Water by Block Copolymer Additives

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2002

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Mastai, Yitzhak
Rudloff, Jan
Antonietti, Markus

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ChemPhysChem. 2002, 3(1), pp. 119-123. ISSN 1439-4235. eISSN 1439-7641. Available under: doi: 10.1002/1439-7641(20020118)3:1<119::AID-CPHC119>3.0.CO;2-R

Zusammenfassung

original image Antifreeze proteins protecting against ice crystallization have biomimetic analogons in block copolymers poly(ethylene oxide)–poly[2-(2-hydroxyethyl)ethylene] and its partially phosphorylated derivative. Both polymers influence the structure of liquid and solid water to a greater extent than the proteins, as shown by an excess increase of the average water density (as shown in the graph), water viscosity changes, additional exothermic enthalpic transitions close to the freezing point, as well as changes of the ice unit cell.

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540 Chemie

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ISO 690MASTAI, Yitzhak, Jan RUDLOFF, Helmut CÖLFEN, Markus ANTONIETTI, 2002. Control over the Structure of Ice and Water by Block Copolymer Additives. In: ChemPhysChem. 2002, 3(1), pp. 119-123. ISSN 1439-4235. eISSN 1439-7641. Available under: doi: 10.1002/1439-7641(20020118)3:1<119::AID-CPHC119>3.0.CO;2-R
BibTex
@article{Mastai2002-01-18Contr-40528,
  year={2002},
  doi={10.1002/1439-7641(20020118)3:1<119::AID-CPHC119>3.0.CO;2-R},
  title={Control over the Structure of Ice and Water by Block Copolymer Additives},
  number={1},
  volume={3},
  issn={1439-4235},
  journal={ChemPhysChem},
  pages={119--123},
  author={Mastai, Yitzhak and Rudloff, Jan and Cölfen, Helmut and Antonietti, Markus}
}
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