Publikation: Multiphase polymer dispersions and nanocomposites by catalytic/free radical emulsion polymerization
Dateien
Datum
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Publikationsstatus
Erschienen in
Zusammenfassung
Free radical emulsion polymerization of styrene (S) or butyl acrylate (BA) in the presence of latices of linear polyethylene (PE) prepared by catalytic emulsion polymerization affords colloidally stable multiphase latices. Coagulation of a PE/PS latex affords nanocomposites composed of small PE phases dispersed in a PS matrix, as evidenced by the large supercoolings of PE crystallization (by DSC). TEM of PE/PBA latices indicates a PBA phase around the PE particles under the emulsion polymerization conditions investigated. Films formed from these dispersions exhibit homogeneously dispersed PE particles. Multiphase latices are obtained by free radical emulsion polymerization of butyl acrylate in the presence of latices of linear polyethylene (PE) prepared by catalytic emulsion polymerization.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
Schlagwörter
Konferenz
Rezension
Zitieren
ISO 690
KOLB, Ludmila, Ralf THOMANN, Stefan MECKING, 2004. Multiphase polymer dispersions and nanocomposites by catalytic/free radical emulsion polymerization. In: Macromolecular Rapid Communications. 2004, 25(21), pp. 1824-1828. ISSN 1022-1336. eISSN 1521-3927. Available under: doi: 10.1002/marc.200400346BibTex
@article{Kolb2004Multi-9631, year={2004}, doi={10.1002/marc.200400346}, title={Multiphase polymer dispersions and nanocomposites by catalytic/free radical emulsion polymerization}, number={21}, volume={25}, issn={1022-1336}, journal={Macromolecular Rapid Communications}, pages={1824--1828}, author={Kolb, Ludmila and Thomann, Ralf and Mecking, Stefan} }
RDF
<rdf:RDF xmlns:dcterms="http://purl.org/dc/terms/" xmlns:dc="http://purl.org/dc/elements/1.1/" xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:bibo="http://purl.org/ontology/bibo/" xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#" xmlns:foaf="http://xmlns.com/foaf/0.1/" xmlns:void="http://rdfs.org/ns/void#" xmlns:xsd="http://www.w3.org/2001/XMLSchema#" > <rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9631"> <dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:19Z</dcterms:available> <dc:creator>Mecking, Stefan</dc:creator> <dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <dc:language>eng</dc:language> <dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:13:19Z</dc:date> <void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/> <dc:creator>Kolb, Ludmila</dc:creator> <dc:creator>Thomann, Ralf</dc:creator> <dcterms:bibliographicCitation>First publ. in: Macromolecular Rapid Communications 25 (2004), pp. 1824-1828</dcterms:bibliographicCitation> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9631/2/Supporting_Inormation_Multiphase_polymer_dispersions_and_nanocomposites_by_catalytic_free_radical_emulsion_polymerization.pdf"/> <dcterms:rights rdf:resource="http://creativecommons.org/licenses/by-nc-nd/2.0/"/> <dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9631/1/Multiphase_polymer_dispersions_and_nanocomposites_by_catalytic_free_radical_emulsion_polymerization.pdf"/> <dc:rights>Attribution-NonCommercial-NoDerivs 2.0 Generic</dc:rights> <dcterms:abstract xml:lang="eng">Free radical emulsion polymerization of styrene (S) or butyl acrylate (BA) in the presence of latices of linear polyethylene (PE) prepared by catalytic emulsion polymerization affords colloidally stable multiphase latices. Coagulation of a PE/PS latex affords nanocomposites composed of small PE phases dispersed in a PS matrix, as evidenced by the large supercoolings of PE crystallization (by DSC). TEM of PE/PBA latices indicates a PBA phase around the PE particles under the emulsion polymerization conditions investigated. Films formed from these dispersions exhibit homogeneously dispersed PE particles. Multiphase latices are obtained by free radical emulsion polymerization of butyl acrylate in the presence of latices of linear polyethylene (PE) prepared by catalytic emulsion polymerization.</dcterms:abstract> <dcterms:issued>2004</dcterms:issued> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9631/2/Supporting_Inormation_Multiphase_polymer_dispersions_and_nanocomposites_by_catalytic_free_radical_emulsion_polymerization.pdf"/> <dc:format>application/pdf</dc:format> <dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/> <bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9631"/> <dcterms:title>Multiphase polymer dispersions and nanocomposites by catalytic/free radical emulsion polymerization</dcterms:title> <dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9631/1/Multiphase_polymer_dispersions_and_nanocomposites_by_catalytic_free_radical_emulsion_polymerization.pdf"/> <dc:contributor>Kolb, Ludmila</dc:contributor> <dc:contributor>Thomann, Ralf</dc:contributor> <dc:contributor>Mecking, Stefan</dc:contributor> <foaf:homepage rdf:resource="http://localhost:8080/"/> </rdf:Description> </rdf:RDF>