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Photoelectron spectroscopy of the aluminum hydride anions: AlH2 , AlH3 , Al2H6 , Al3H9 , and Al4H12

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2013

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Zhang, Xinxing
Wang, Haopeng
Collins, Evan
Lim, Alane
Kiran, Boggavarapu
Schnöckel, Hansgeorg
Eichhorn, Bryan
Bowen, Kit

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http://nbn-resolving.de/urn:nbn:de:bsz:352-271192
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https://doi.org/10.1063/1.4796200
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The Journal of Chemical Physics. 2013, 138(12), 124303. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4796200

Zusammenfassung

We report measurements of the negative ion photoelectron spectra of the simple aluminum hydride anions: AlH2−, AlH3−, Al2H6−, Al3H9−, and Al4H12−. From these spectra, we measured the vertical detachment energies of the anions, and we estimated the electron affinities of their neutral counterparts. Our results for AlH2 −, AlH3 −, and Al2H6 − were also compared with previous predictions by theory.

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ISO 690ZHANG, Xinxing, Haopeng WANG, Evan COLLINS, Alane LIM, Gerd GANTEFÖR, Boggavarapu KIRAN, Hansgeorg SCHNÖCKEL, Bryan EICHHORN, Kit BOWEN, 2013. Photoelectron spectroscopy of the aluminum hydride anions: AlH2 , AlH3 , Al2H6 , Al3H9 , and Al4H12. In: The Journal of Chemical Physics. 2013, 138(12), 124303. ISSN 0021-9606. eISSN 1089-7690. Available under: doi: 10.1063/1.4796200
BibTex
@article{Zhang2013-03-28Photo-27119,
  year={2013},
  doi={10.1063/1.4796200},
  title={Photoelectron spectroscopy of the aluminum hydride anions: AlH<sub>2</sub> , AlH<sub>3</sub> , Al<sub>2</sub>H<sub>6</sub> , Al<sub>3</sub>H<sub>9</sub> , and Al<sub>4</sub>H<sub>12</sub>},
  number={12},
  volume={138},
  issn={0021-9606},
  journal={The Journal of Chemical Physics},
  author={Zhang, Xinxing and Wang, Haopeng and Collins, Evan and Lim, Alane and Ganteför, Gerd and Kiran, Boggavarapu and Schnöckel, Hansgeorg and Eichhorn, Bryan and Bowen, Kit},
  note={Article Number: 124303}
}
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