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Tuneable helices of plasmonic nanoparticles using liquid crystal templates : molecular dynamics investigation of an unusual odd–even effect in liquid crystalline dimers

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2022

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Pawlak, Mateusz
Bagiński, Maciej
Llombart, Pablo
Beutel, Dominik
Górecka, Ewa
Rockstuhl, Carsten
Mieczkowski, Józef
Pociecha, Damian
Lewandowski, Wiktor

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Chemical Communications. Royal Society of Chemistry (RSC). 2022, 58(53), pp. 7364-7367. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/D2CC00560C

Zusammenfassung

Liquid crystalline (LC) dimers formed helical nanofilaments depending on the parity of the alkyl linker, revealing an unusual odd–even effect. Molecular dynamics simulations were used to investigate the observed tendency. Elongation of the linker translates to an increase of the pitch of the helices, which allows achieving tuneable helical assemblies of Au nanoparticles doped to the LC matrix. The impact of the tuneable pitch of helices on the chiral optical properties of composites was investigated with full-wave simulations based on the T-matrix method.

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540 Chemie

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ISO 690PAWLAK, Mateusz, Maciej BAGIŃSKI, Pablo LLOMBART, Dominik BEUTEL, Guillermo GONZALEZ-RUBIO, Ewa GÓRECKA, Carsten ROCKSTUHL, Józef MIECZKOWSKI, Damian POCIECHA, Wiktor LEWANDOWSKI, 2022. Tuneable helices of plasmonic nanoparticles using liquid crystal templates : molecular dynamics investigation of an unusual odd–even effect in liquid crystalline dimers. In: Chemical Communications. Royal Society of Chemistry (RSC). 2022, 58(53), pp. 7364-7367. ISSN 1359-7345. eISSN 1364-548X. Available under: doi: 10.1039/D2CC00560C
BibTex
@article{Pawlak2022-06-30Tunea-57758,
  year={2022},
  doi={10.1039/D2CC00560C},
  title={Tuneable helices of plasmonic nanoparticles using liquid crystal templates : molecular dynamics investigation of an unusual odd–even effect in liquid crystalline dimers},
  number={53},
  volume={58},
  issn={1359-7345},
  journal={Chemical Communications},
  pages={7364--7367},
  author={Pawlak, Mateusz and Bagiński, Maciej and Llombart, Pablo and Beutel, Dominik and Gonzalez-Rubio, Guillermo and Górecka, Ewa and Rockstuhl, Carsten and Mieczkowski, Józef and Pociecha, Damian and Lewandowski, Wiktor}
}
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