Room-temperature phosphorescence and static excimer excitation of pyrene-modified (NCN) pincer bismuth complexes

Kurzanzeige
dc.contributor.authorGeppert, Marcel
dc.contributor.authorMüller, Michelle
dc.contributor.authorLinseis, Michael
dc.contributor.authorWinter, Rainer F.
dc.date.accessioned2025-01-28T08:37:06Z
dc.date.available2025-01-28T08:37:06Z
dc.date.issued2025
dc.description.abstractWe present the synthesis, characterization, and photophysical properties of two pyrene-modified (NCN) pincer bismuth complexes, where the pyrenyl residues are either part of the cyclometalating pincer ligand (1) or bound as monodentate ligands to the BiIII ion (2). Both complexes are dually emissive at 77 K. For complex 2, pyrenyl phosphorescence persists at r.t. in degassed CH2Cl2, albeit with reduced intensity. This renders 2 one of only a handful of Bi complexes showing this property.
dc.description.versionpublisheddeu
dc.identifier.doi10.1039/d4dt03304c
dc.identifier.urihttps://kops.uni-konstanz.de/handle/123456789/72064
dc.language.isoeng
dc.subject.ddc540
dc.titleRoom-temperature phosphorescence and static excimer excitation of pyrene-modified (NCN) pincer bismuth complexeseng
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@article{Geppert2025Roomt-72064,
  title={Room-temperature phosphorescence and static excimer excitation of pyrene-modified (NCN) pincer bismuth complexes},
  year={2025},
  doi={10.1039/d4dt03304c},
  number={5},
  volume={54},
  issn={1477-9226},
  journal={Dalton Transactions},
  pages={1779--1783},
  author={Geppert, Marcel and Müller, Michelle and Linseis, Michael and Winter, Rainer F.}
}
kops.citation.iso690GEPPERT, Marcel, Michelle MÜLLER, Michael LINSEIS, Rainer F. WINTER, 2025. Room-temperature phosphorescence and static excimer excitation of pyrene-modified (NCN) pincer bismuth complexes. In: Dalton Transactions. Royal Society of Chemistry (RSC). 2025, 54(5), S. 1779-1783. ISSN 1477-9226. eISSN 1477-9234. Verfügbar unter: doi: 10.1039/d4dt03304cdeu
kops.citation.iso690GEPPERT, Marcel, Michelle MÜLLER, Michael LINSEIS, Rainer F. WINTER, 2025. Room-temperature phosphorescence and static excimer excitation of pyrene-modified (NCN) pincer bismuth complexes. In: Dalton Transactions. Royal Society of Chemistry (RSC). 2025, 54(5), pp. 1779-1783. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/d4dt03304ceng
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