Publikation:

Asymmetric Synthesis of Diastereomerically and Enantiomerically Pure, 3-Substituted (2S,3R)-N-Methylserine Esters

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Asymmetric_Synthesis_of_Diastereomerically_and_Enantiomerically_.pdf
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Datum

1992

Autor:innen

Beulshausen, Tessa
Schöllkopf, Ulrich

Herausgeber:innen

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URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-47264
DOI (zitierfähiger Link)
https://doi.org/10.1002/jlac.199219920190
ArXiv-ID

Internationale Patentnummer

Link zur Lizenz
Attribution-NonCommercial-NoDerivs 2.0 Generic

Angaben zur Forschungsförderung

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Open Access-Veröffentlichung
Open Access Green

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Chemie: Publikationen
Core Facility der Universität Konstanz

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Titel in einer weiteren Sprache

Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published

Erschienen in

Liebigs Annalen der Chemie. 1992, 1992(5), pp. 523-526. ISSN 0170-2041. eISSN 1099-0690. Available under: doi: 10.1002/jlac.199219920190

Zusammenfassung

A novel method for the synthesis of N-methylserines has been developed. The oxazolidines 4 are formed by condensation of the serine methyl esters 1 with formaldehyde. These intermediates are subsequently reduced to the N-methylserine methyl esters 9 by an acid-catalyzed ring opening via their iminium ions 2 with triethylsilane/trifluoroacetic acid.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

Serine derivatives, Bislactim ether method

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ISO 690BEULSHAUSEN, Tessa, Ulrich GROTH, Ulrich SCHÖLLKOPF, 1992. Asymmetric Synthesis of Diastereomerically and Enantiomerically Pure, 3-Substituted (2S,3R)-N-Methylserine Esters. In: Liebigs Annalen der Chemie. 1992, 1992(5), pp. 523-526. ISSN 0170-2041. eISSN 1099-0690. Available under: doi: 10.1002/jlac.199219920190
BibTex
@article{Beulshausen1992Asymm-9671,
  year={1992},
  doi={10.1002/jlac.199219920190},
  title={Asymmetric Synthesis of Diastereomerically and Enantiomerically Pure, 3-Substituted (2S,3R)-N-Methylserine Esters},
  number={5},
  volume={1992},
  issn={0170-2041},
  journal={Liebigs Annalen der Chemie},
  pages={523--526},
  author={Beulshausen, Tessa and Groth, Ulrich and Schöllkopf, Ulrich}
}
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