Publikation:

Disperse amphiphilic submicron particles as non-covalent supports for cationic homogeneous catalysts

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Disperse_amphiphilic_submicron_particles_as_non_covalent_supports_for_cationic_homogeneous_catalysts.pdf
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Datum

2005

Autor:innen

Sablong, Rafaël
Vlugt, Jarl Ivar van der
Thomann, Ralf
Vogt, Dieter

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URI (zitierfähiger Link)
http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-43281
DOI (zitierfähiger Link)
https://doi.org/10.1002/adsc.200404284
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Link zur Lizenz
Attribution-NonCommercial-NoDerivs 2.0 Generic

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Open Access-Veröffentlichung
Open Access Green

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Chemie: Publikationen
Core Facility der Universität Konstanz

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Titel in einer weiteren Sprache

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Zeitschriftenartikel
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Published

Erschienen in

Advanced Synthesis and Catalysis. 2005, 347(5), pp. 633-636. ISSN 1615-4150. eISSN 1615-4169. Available under: doi: 10.1002/adsc.200404284

Zusammenfassung

A simple method for the effective immobilization of homogeneous catalysts on polystyrene colloids via non-covalent binding is demonstrated. Stable latices with sufficiently high loading of accessible borate anions are prepared via emulsion polymerization. Incorporation of cationic rhodium complexes, supported via their borate counter-anion is efficient, and these supported homogeneous catalysts maintain constant catalytic activity for C=C hydrogenation during several recycles, with very low metal leaching.

Zusammenfassung in einer weiteren Sprache

Fachgebiet (DDC)
540 Chemie

Schlagwörter

catalyst immobilization, counter-anion, emulsion polymerization, polymerizable borate, recycling

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ISO 690SABLONG, Rafaël, Jarl Ivar van der VLUGT, Ralf THOMANN, Stefan MECKING, Dieter VOGT, 2005. Disperse amphiphilic submicron particles as non-covalent supports for cationic homogeneous catalysts. In: Advanced Synthesis and Catalysis. 2005, 347(5), pp. 633-636. ISSN 1615-4150. eISSN 1615-4169. Available under: doi: 10.1002/adsc.200404284
BibTex
@article{Sablong2005Dispe-9994,
  year={2005},
  doi={10.1002/adsc.200404284},
  title={Disperse amphiphilic submicron particles as non-covalent supports for cationic homogeneous catalysts},
  number={5},
  volume={347},
  issn={1615-4150},
  journal={Advanced Synthesis and Catalysis},
  pages={633--636},
  author={Sablong, Rafaël and Vlugt, Jarl Ivar van der and Thomann, Ralf and Mecking, Stefan and Vogt, Dieter}
}
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