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Mode of alkylation of alcohols with O-cyclopropylmethyl trichloroacetimidate and O-cyclobutyl trichloroacetimidate

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2012

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Ali, Ibrahim A. I.
Zhu, Xiangming
Ashry, El Sayed H. el

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Arkivoc. 2012(6), pp. 35-44. ISSN 1551-7004. eISSN 1551-7012

Zusammenfassung

Acid promoted alkylation of hydroxy group containing acceptors 3-14 with O-cyclopropylmethyl and O-cyclobutyl trichloroacetimidates 1 and 2, respectively, afforded ethers with cyclopropylmethyl, cyclobutyl, and homoallyl residues as a result of the rearrangement of the cation intermediates. The dependence of product formation on acceptor structure is discussed.

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540 Chemie

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ISO 690ALI, Ibrahim A. I., Xiangming ZHU, El Sayed H. el ASHRY, Richard R. SCHMIDT, 2012. Mode of alkylation of alcohols with O-cyclopropylmethyl trichloroacetimidate and O-cyclobutyl trichloroacetimidate. In: Arkivoc. 2012(6), pp. 35-44. ISSN 1551-7004. eISSN 1551-7012
BibTex
@article{Ali2012alkyl-21630,
  year={2012},
  title={Mode of alkylation of alcohols with O-cyclopropylmethyl trichloroacetimidate and O-cyclobutyl trichloroacetimidate},
  number={6},
  issn={1551-7004},
  journal={Arkivoc},
  pages={35--44},
  author={Ali, Ibrahim A. I. and Zhu, Xiangming and Ashry, El Sayed H. el and Schmidt, Richard R.}
}
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