@article{NeiraCarrillo2019-08-15Funct-46983,
  year={2019},
  doi={10.3390/nano9081169},
  title={Functionalized Multiwalled CNTs in Classical and Nonclassical CaCO<sub>3</sub> Crystallization},
  number={8},
  volume={9},
  journal={Nanomaterials},
  author={Neira-Carrillo, Andrónico and Vásquez-Quitral, Patricio and Sánchez, Marianela and Farhadi-Khouzani, Masoud and Aguilar-Bolados, Héctor and Yazdani-Pedram, Mehrdad and Cölfen, Helmut},
  note={Article Number: 1169}
}

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    <dc:contributor>Sánchez, Marianela</dc:contributor>
    <dc:contributor>Yazdani-Pedram, Mehrdad</dc:contributor>
    <dc:creator>Neira-Carrillo, Andrónico</dc:creator>
    <dc:creator>Farhadi-Khouzani, Masoud</dc:creator>
    <dc:creator>Yazdani-Pedram, Mehrdad</dc:creator>
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    <dcterms:title>Functionalized Multiwalled CNTs in Classical and Nonclassical CaCO&lt;sub&gt;3&lt;/sub&gt; Crystallization</dcterms:title>
    <dcterms:abstract xml:lang="eng">Multiwalled carbon nanotubes (MWCNTs) are interesting high-tech nanomaterials. MWCNTs oxidized and functionalized with itaconic acid and monomethylitaconate were demonstrated to be efficient additives for controlling nucleation of calcium carbonate (CaCO&lt;sub&gt;3&lt;/sub&gt;) via gas diffusion (GD) in classical as well as nonclassical crystallization, yielding aragonite and truncated calcite. For the first time, all amorphous calcium carbonate (ACC) proto-structures, such as proto calcite-ACC, proto vaterite-ACC and proto aragonite-ACC, were synthesized via prenucleation cluster (PNC) intermediates and stabilized at room temperature. The MWCNTs also showed concentration-dependent nucleation promotion and inhibition similar to biomolecules in nature. Incorporation of fluorescein-5-thiosemicarbazide (5-FTSC) dye-labeled MWCNTs into the CaCO&lt;sub&gt;3&lt;/sub&gt; lattice resulted in fluorescent hybrid nanosized CaCO&lt;sub&gt;3&lt;/sub&gt;. We demonstrate that functionalized MWCNTs offer a good alternative for controlled selective crystallization and for understanding an inorganic mineralization process.</dcterms:abstract>
    <dc:contributor>Neira-Carrillo, Andrónico</dc:contributor>
    <dc:contributor>Aguilar-Bolados, Héctor</dc:contributor>
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    <dc:creator>Sánchez, Marianela</dc:creator>
    <dc:contributor>Vásquez-Quitral, Patricio</dc:contributor>
    <dc:creator>Aguilar-Bolados, Héctor</dc:creator>
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    <dc:creator>Cölfen, Helmut</dc:creator>
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    <dc:contributor>Cölfen, Helmut</dc:contributor>
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    <dc:contributor>Farhadi-Khouzani, Masoud</dc:contributor>
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