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Chemistry in Confining Reaction Fields with Special Emphasis on Nanoporous Materials

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2008

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http://nbn-resolving.de/urn:nbn:de:bsz:352-opus-117574
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https://doi.org/10.1002/chem.200800674
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Chemistry: A European Journal. 2008, 14(32), pp. 9816-9829. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.200800674

Zusammenfassung

The everyday routine of most chemists is dictated by large numbers. The chemical rules for ensembles of molar size (NNA=6.022×1023) are well known and can be understood in most cases by using Boltzmann distribution. It is an interesting question how a small ensemble of a chemical system behaves and if it differs from the respective large-ensemble counterpart. The experimental approach presented in the current paper involves the division of a macroscopic volume into compartments that contain only a small number of reactants. The compartments represent the pores of tailor-made nanoporous materials.

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540 Chemie

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ISO 690POLARZ, Sebastian, Andreas KUSCHEL, 2008. Chemistry in Confining Reaction Fields with Special Emphasis on Nanoporous Materials. In: Chemistry: A European Journal. 2008, 14(32), pp. 9816-9829. ISSN 0947-6539. eISSN 1521-3765. Available under: doi: 10.1002/chem.200800674
BibTex
@article{Polarz2008Chemi-1066,
  year={2008},
  doi={10.1002/chem.200800674},
  title={Chemistry in Confining Reaction Fields with Special Emphasis on Nanoporous Materials},
  number={32},
  volume={14},
  issn={0947-6539},
  journal={Chemistry: A European Journal},
  pages={9816--9829},
  author={Polarz, Sebastian and Kuschel, Andreas}
}
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