Publikation:

A ruthenium racemisation catalyst for the synthesis of primary amines from secondary amines

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Pingen_0-361634.pdf
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2016

Autor:innen

Altıntaş, Çiğdem
Schaller, Max Rudolf
Vogt, Dieter

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http://nbn-resolving.de/urn:nbn:de:bsz:352-0-361634
DOI (zitierfähiger Link)
https://doi.org/10.1039/c6dt01525e
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Attribution 3.0 Unported

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Open Access-Veröffentlichung
Open Access Hybrid

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Chemie: Publikationen
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Published

Erschienen in

Dalton Transactions. 2016, 45(29), pp. 11765-11771. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/c6dt01525e

Zusammenfassung

A Ru-based half sandwich complex used in amine and alcohol racemization reactions was found to be active in the splitting of secondary amines to primary amines using NH3. Conversions up to 80% along with very high selectivities were achieved. However, after about 80% conversion the catalyst lost activity. Similar to Shvo's catalyst, the complex might deactivate under the influence of ammonia. It was revealed that not NH3 but mainly the primary amine is responsible for the deactivation.

Zusammenfassung in einer weiteren Sprache

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540 Chemie

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ISO 690PINGEN, Dennis, Çiğdem ALTINTAŞ, Max Rudolf SCHALLER, Dieter VOGT, 2016. A ruthenium racemisation catalyst for the synthesis of primary amines from secondary amines. In: Dalton Transactions. 2016, 45(29), pp. 11765-11771. ISSN 1477-9226. eISSN 1477-9234. Available under: doi: 10.1039/c6dt01525e
BibTex
@article{Pingen2016ruthe-35435,
  year={2016},
  doi={10.1039/c6dt01525e},
  title={A ruthenium racemisation catalyst for the synthesis of primary amines from secondary amines},
  number={29},
  volume={45},
  issn={1477-9226},
  journal={Dalton Transactions},
  pages={11765--11771},
  author={Pingen, Dennis and Altıntaş, Çiğdem and Schaller, Max Rudolf and Vogt, Dieter}
}
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