Publikation: Asymmetric Synthesis via Heterocyclic Intermediates, LII. Synthesis of tert-Leucine and Related Amino Acids
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1993
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Published
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Liebigs Annalen der Chemie. 1993(7), pp. 715-719. ISSN 0170-2041. eISSN 1099-0690
Zusammenfassung
The 2,5-dialkoxypyrazines 3a and b were prepared in three steps from methyl glycinate hydrochloride (1) in an overall yield of 18 and 63%. Upon the addition of lithium organyls to 3b and subsequent acidic hydrolysis the ethyl glycinates rac-7 were obtained.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
tert-Leucine, Amino acids, Glycine cation equicalents, Bislactim ether method
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GROTH, Ulrich, Thomas HUHN, Bettina PORSCH, Carsten SCHMECK, Ulrich SCHÖLLKOPF, 1993. Asymmetric Synthesis via Heterocyclic Intermediates, LII. Synthesis of tert-Leucine and Related Amino Acids. In: Liebigs Annalen der Chemie. 1993(7), pp. 715-719. ISSN 0170-2041. eISSN 1099-0690BibTex
@article{Groth1993Asymm-9562,
year={1993},
title={Asymmetric Synthesis via Heterocyclic Intermediates, LII. Synthesis of tert-Leucine and Related Amino Acids},
number={7},
issn={0170-2041},
journal={Liebigs Annalen der Chemie},
pages={715--719},
author={Groth, Ulrich and Huhn, Thomas and Porsch, Bettina and Schmeck, Carsten and Schöllkopf, Ulrich}
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<dcterms:abstract xml:lang="eng">The 2,5-dialkoxypyrazines 3a and b were prepared in three steps from methyl glycinate hydrochloride (1) in an overall yield of 18 and 63%. Upon the addition of lithium organyls to 3b and subsequent acidic hydrolysis the ethyl glycinates rac-7 were obtained.</dcterms:abstract>
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