Publikation: Bis(Eta3-indenyl)bis(tetrahydrofuran)magnesium(II)
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2004
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Acta Crystallographica Section E Structure Reports Online. 2004, 60(8), pp. m1108-m1110. ISSN 1600-5368. Available under: doi: 10.1107/S1600536804016149
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In the crystal structure of the title compound, [Mg(C4H8O)2(C9H7)2], the two indenyl ligands are bound to the Mg atom in a manner intermediate between Eta1- and Eta3-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)2 adduct (THF is tetrahydrofuran). A crystallographic C2 axis bisects the O-Mg-O angle.
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GRITZO, Holger, Frank SCHAPER, Hans-Herbert BRINTZINGER, 2004. Bis(Eta3-indenyl)bis(tetrahydrofuran)magnesium(II). In: Acta Crystallographica Section E Structure Reports Online. 2004, 60(8), pp. m1108-m1110. ISSN 1600-5368. Available under: doi: 10.1107/S1600536804016149BibTex
@article{Gritzo2004BisEt-23845,
year={2004},
doi={10.1107/S1600536804016149},
title={Bis(Eta<sup>3</sup>-indenyl)bis(tetrahydrofuran)magnesium(II)},
number={8},
volume={60},
issn={1600-5368},
journal={Acta Crystallographica Section E Structure Reports Online},
pages={m1108--m1110},
author={Gritzo, Holger and Schaper, Frank and Brintzinger, Hans-Herbert}
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<dcterms:abstract xml:lang="eng">In the crystal structure of the title compound, [Mg(C<sub>4</sub>H<sub>8</sub>O)<sub>2</sub>(C<sub>9</sub>H<sub>7</sub>)<sub>2</sub>], the two indenyl ligands are bound to the Mg atom in a manner intermediate between Eta<sup>1</sup>- and Eta<sup>3</sup>-coordination; the latter is untypical, as it includes one of the ring-sharing C atoms. The O-Mg-O angle [101.01°] is larger than for any other magnesocene-(THF)<sub>2</sub> adduct (THF is tetrahydrofuran). A crystallographic C<sub>2</sub> axis bisects the O-Mg-O angle.</dcterms:abstract>
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