Publikation: Total Synthesis of the Angucylinone Antibiotic (+)-Rubiginone B2
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2003
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Kalogerakis, Aris
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Synlett. 2003(12), pp. 1886-1888. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2003-41473
Zusammenfassung
A new chiral synthesis of (+)-rubiginone B2 is reported. The intramolecular cobalt-mediated [2+2+2]-cycloaddition of a triyne precursor, synthesized from (+)-citronellal, afforded a chiral anthracene, which led after a two-step oxidation to the angucyclinone antibiotic.
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Fachgebiet (DDC)
540 Chemie
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angucyclinone antibiotics, benz[a]anthraquinones, natural products, catalysis, cobalt, cycloaddition
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KALOGERAKIS, Aris, Ulrich GROTH, 2003. Total Synthesis of the Angucylinone Antibiotic (+)-Rubiginone B2. In: Synlett. 2003(12), pp. 1886-1888. ISSN 0936-5214. eISSN 1437-2096. Available under: doi: 10.1055/s-2003-41473BibTex
@article{Kalogerakis2003Total-9707, year={2003}, doi={10.1055/s-2003-41473}, title={Total Synthesis of the Angucylinone Antibiotic (+)-Rubiginone B2}, number={12}, issn={0936-5214}, journal={Synlett}, pages={1886--1888}, author={Kalogerakis, Aris and Groth, Ulrich} }
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