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Hyperhalogens : Discovery of a new class of highly electronegative species

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2010

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Willis, Mary
Kandalam, Anil K.
Jena, Puru

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Angewandte Chemie International Edition. 2010, 49(47), pp. 8966-8970. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.201002212

Zusammenfassung

Hyper trumps super: A central atom, typically a metal, surrounded by halogen or oxygen atoms is called a superhalogen. Theoretical calculations and experiments reveal that a new class of highly electronegative species can be created when the central metal atom is surrounded by superhalogen moieties. These hyperhalogens can have electron affinities even larger than those of their superhalogen building blocks.

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Fachgebiet (DDC)
530 Physik

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borates, density functional calculations, gold clusters, photoelectron spectroscopy, superhalogens

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ISO 690WILLIS, Mary, Matthias GÖTZ, Anil K. KANDALAM, Gerd GANTEFÖR, Puru JENA, 2010. Hyperhalogens : Discovery of a new class of highly electronegative species. In: Angewandte Chemie International Edition. 2010, 49(47), pp. 8966-8970. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.201002212
BibTex
@article{Willis2010-11-15Hyper-12480,
  year={2010},
  doi={10.1002/anie.201002212},
  title={Hyperhalogens : Discovery of a new class of highly electronegative species},
  number={47},
  volume={49},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={8966--8970},
  author={Willis, Mary and Götz, Matthias and Kandalam, Anil K. and Ganteför, Gerd and Jena, Puru}
}
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