Publikation: Functionalization of Polymer Nanoparticles by Thiol-Ene Addition
Lade...
Dateien
Datum
2010
Autor:innen
Herausgeber:innen
ISSN der Zeitschrift
Electronic ISSN
ISBN
Bibliografische Daten
Verlag
Schriftenreihe
Auflagebezeichnung
URI (zitierfähiger Link)
DOI (zitierfähiger Link)
Internationale Patentnummer
Link zur Lizenz
Angaben zur Forschungsförderung
Projekt
Open Access-Veröffentlichung
Open Access Green
Sammlungen
Core Facility der Universität Konstanz
Titel in einer weiteren Sprache
Publikationstyp
Zeitschriftenartikel
Publikationsstatus
Published
Erschienen in
Macromolecules. 2010, 43(19), pp. 8071-8078. ISSN 0024-9297. eISSN 1520-5835. Available under: doi: 10.1021/ma100966w
Zusammenfassung
Syndiotactic 1,2-polybutadiene nanoparticles (volume average diameter 13 nm) were functionalized in aqueous dispersion by free radical mercaptan addition. By appropriate choice of both watersoluble radical initiator and mercaptan concentration, nanoparticles with a degree of functionalization of up to 85% were prepared using 3-mercaptopropionic acid methyl ester and 3-mercaptopropionic acid. Only a minor portion of double bonds formed cycles instead of the desired thiol-ene addition products. The composition and structure of the nanoparticles were elucidated by combination of elemental analysis, NMR, IR, DLS, and TEM. Highly hydrophilic mercaptans (3-mercaptopropanesulfonic acid sodium salts), in contrast, only reacted with surface accessible double bonds to afford stable and redispersible nanoparticles solely stabilized with covalently bound moieties on their surface. Analogous grafting of the tripeptide glutathione was demonstrated.
Zusammenfassung in einer weiteren Sprache
Fachgebiet (DDC)
540 Chemie
Schlagwörter
Konferenz
Rezension
undefined / . - undefined, undefined
Zitieren
ISO 690
KORTHALS, Brigitte, Maria Carmen MORANT-MINANA, Marius SCHMID, Stefan MECKING, 2010. Functionalization of Polymer Nanoparticles by Thiol-Ene Addition. In: Macromolecules. 2010, 43(19), pp. 8071-8078. ISSN 0024-9297. eISSN 1520-5835. Available under: doi: 10.1021/ma100966wBibTex
@article{Korthals2010Funct-9999,
year={2010},
doi={10.1021/ma100966w},
title={Functionalization of Polymer Nanoparticles by Thiol-Ene Addition},
number={19},
volume={43},
issn={0024-9297},
journal={Macromolecules},
pages={8071--8078},
author={Korthals, Brigitte and Morant-Minana, Maria Carmen and Schmid, Marius and Mecking, Stefan}
}RDF
<rdf:RDF
xmlns:dcterms="http://purl.org/dc/terms/"
xmlns:dc="http://purl.org/dc/elements/1.1/"
xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#"
xmlns:bibo="http://purl.org/ontology/bibo/"
xmlns:dspace="http://digital-repositories.org/ontologies/dspace/0.1.0#"
xmlns:foaf="http://xmlns.com/foaf/0.1/"
xmlns:void="http://rdfs.org/ns/void#"
xmlns:xsd="http://www.w3.org/2001/XMLSchema#" >
<rdf:Description rdf:about="https://kops.uni-konstanz.de/server/rdf/resource/123456789/9999">
<dcterms:rights rdf:resource="https://rightsstatements.org/page/InC/1.0/"/>
<dcterms:bibliographicCitation>First publ. in: Macromolecules ; 43 (2010), 19. - S. 8071-8078</dcterms:bibliographicCitation>
<dc:contributor>Morant-Minana, Maria Carmen</dc:contributor>
<dspace:isPartOfCollection rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<void:sparqlEndpoint rdf:resource="http://localhost/fuseki/dspace/sparql"/>
<dc:date rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-03-24T18:15:52Z</dc:date>
<dc:creator>Schmid, Marius</dc:creator>
<dcterms:isPartOf rdf:resource="https://kops.uni-konstanz.de/server/rdf/resource/123456789/29"/>
<dspace:hasBitstream rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9999/1/2010_Macromolecules_43_8071_Korthals_thiolene_nanoparticles.pdf"/>
<dc:creator>Korthals, Brigitte</dc:creator>
<dcterms:title>Functionalization of Polymer Nanoparticles by Thiol-Ene Addition</dcterms:title>
<dc:contributor>Mecking, Stefan</dc:contributor>
<dc:contributor>Schmid, Marius</dc:contributor>
<bibo:uri rdf:resource="http://kops.uni-konstanz.de/handle/123456789/9999"/>
<dcterms:issued>2010</dcterms:issued>
<foaf:homepage rdf:resource="http://localhost:8080/"/>
<dcterms:abstract xml:lang="eng">Syndiotactic 1,2-polybutadiene nanoparticles (volume average diameter 13 nm) were functionalized in aqueous dispersion by free radical mercaptan addition. By appropriate choice of both watersoluble radical initiator and mercaptan concentration, nanoparticles with a degree of functionalization of up to 85% were prepared using 3-mercaptopropionic acid methyl ester and 3-mercaptopropionic acid. Only a minor portion of double bonds formed cycles instead of the desired thiol-ene addition products. The composition and structure of the nanoparticles were elucidated by combination of elemental analysis, NMR, IR, DLS, and TEM. Highly hydrophilic mercaptans (3-mercaptopropanesulfonic acid sodium salts), in contrast, only reacted with surface accessible double bonds to afford stable and redispersible nanoparticles solely stabilized with covalently bound moieties on their surface. Analogous grafting of the tripeptide glutathione was demonstrated.</dcterms:abstract>
<dcterms:available rdf:datatype="http://www.w3.org/2001/XMLSchema#dateTime">2011-07-31T22:25:04Z</dcterms:available>
<dc:creator>Mecking, Stefan</dc:creator>
<dc:format>application/pdf</dc:format>
<dc:language>eng</dc:language>
<dcterms:hasPart rdf:resource="https://kops.uni-konstanz.de/bitstream/123456789/9999/1/2010_Macromolecules_43_8071_Korthals_thiolene_nanoparticles.pdf"/>
<dc:creator>Morant-Minana, Maria Carmen</dc:creator>
<dc:rights>terms-of-use</dc:rights>
<dc:contributor>Korthals, Brigitte</dc:contributor>
</rdf:Description>
</rdf:RDF>Interner Vermerk
xmlui.Submission.submit.DescribeStep.inputForms.label.kops_note_fromSubmitter
Prüfungsdatum der Dissertation
Finanzierungsart
Kommentar zur Publikation
Allianzlizenz
Corresponding Authors der Uni Konstanz vorhanden
Internationale Co-Autor:innen
Universitätsbibliographie
Ja
