Publikation:

Siloxane-Based Main-Chain Poly(ionic liquid)s via a Debus–Radziszewski Reaction

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2022

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Reiter, Manuel
Khorsand Kheirabad, Atefeh
Yuan, Jiayin

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ACS Polymers Au. American Chemical Society (ACS). 2022, 2(2), pp. 80-87. ISSN 2694-2453. eISSN 2694-2453. Available under: doi: 10.1021/acspolymersau.1c00029

Zusammenfassung

Herein, we synthesized a series of siloxane-based poly(ionic liquid)s (PILs) with imidazolium-type species in the main chain via the multicomponent Debus–Radziszewski reaction. We employed oligodimethylsiloxane diamine precursors to integrate flexible spacers in the polymer backbone and ultimately succeeded in obtaining main-chain PILs with low glass transition temperatures (Tgs) in the range of −40 to −18 °C. Such PILs were combined with conventional hydrophobic vinylimidazolium-based PILs for the fabrication of porous membranes via interpolyelectrolyte complexation with poly(acrylic acid), which leads to enhanced mechanical performance in the tensile testing measurements. This study will enrich the structure library of main-chain PILs and open up more opportunities for potential industrial applications of porous imidazolium-based membranes.

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540 Chemie

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Siloxanes, Precursors, Membranes, Mixtures, Polymers

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ISO 690REITER, Manuel, Atefeh KHORSAND KHEIRABAD, Miriam M. UNTERLASS, Jiayin YUAN, 2022. Siloxane-Based Main-Chain Poly(ionic liquid)s via a Debus–Radziszewski Reaction. In: ACS Polymers Au. American Chemical Society (ACS). 2022, 2(2), pp. 80-87. ISSN 2694-2453. eISSN 2694-2453. Available under: doi: 10.1021/acspolymersau.1c00029
BibTex
@article{Reiter2022-04-13Silox-55665,
  year={2022},
  doi={10.1021/acspolymersau.1c00029},
  title={Siloxane-Based Main-Chain Poly(ionic liquid)s via a Debus–Radziszewski Reaction},
  number={2},
  volume={2},
  issn={2694-2453},
  journal={ACS Polymers Au},
  pages={80--87},
  author={Reiter, Manuel and Khorsand Kheirabad, Atefeh and Unterlass, Miriam M. and Yuan, Jiayin}
}
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