Macroscopically uniform electrodeposited ZnO films on conducting glass by surface tension modification and consequent demonstration of significantly improved p–n heterojunctions

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Musselman_191932.pdf
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2011
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Musselman, Kevin P.
Gershon, Talia
MacManus-Driscoll, Judith L.
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Electrochimica Acta. 2011, 56(11), pp. 3758-3763. ISSN 0013-4686. Available under: doi: 10.1016/j.electacta.2011.02.067
Zusammenfassung

An alternative water–ethanol zinc nitrate solution is demonstrated to completely eliminate macroscopic defects that are normally prevalent in ZnO films electrochemically deposited from aqueous zinc nitrate solutions. The inclusion of 25% ethanol (by volume) reduces the surface tension of the mixture and eliminates bubble formation on the conducting glass surface during deposition. To demonstrate the importance of film uniformity, the ZnO films are employed in ZnO–Cu2O n–p heterojunctions and an order of magnitude improvement in diode behaviour is observed.

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Fachgebiet (DDC)
530 Physik
Schlagwörter
zinc oxide, conducting glass, electrodeposition, surface tension, photovoltaic
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ISO 690MUSSELMAN, Kevin P., Talia GERSHON, Lukas SCHMIDT-MENDE, Judith L. MACMANUS-DRISCOLL, 2011. Macroscopically uniform electrodeposited ZnO films on conducting glass by surface tension modification and consequent demonstration of significantly improved p–n heterojunctions. In: Electrochimica Acta. 2011, 56(11), pp. 3758-3763. ISSN 0013-4686. Available under: doi: 10.1016/j.electacta.2011.02.067
BibTex
@article{Musselman2011Macro-19193,
  year={2011},
  doi={10.1016/j.electacta.2011.02.067},
  title={Macroscopically uniform electrodeposited ZnO films on conducting glass by surface tension modification and consequent demonstration of significantly improved p–n heterojunctions},
  number={11},
  volume={56},
  issn={0013-4686},
  journal={Electrochimica Acta},
  pages={3758--3763},
  author={Musselman, Kevin P. and Gershon, Talia and Schmidt-Mende, Lukas and MacManus-Driscoll, Judith L.}
}
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