Publikation: Ultraviolet photodetachment spectroscopy on jet-cooled metal-cluster anions
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1988
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Faraday Discussions of the Chemical Society. 1988, 86, pp. 197-208. Available under: doi: 10.1039/DC9888600197
Zusammenfassung
Metal-cluster anions have been produced by laser vaporization and cooled in a supersonic expansion, without converting neutral clusters into anions via a secondary ionizing agent. After mass-selection, photoelectrons were detached (h= 3.68 eV) from defined anion bunches and analysed in a magnetic bottle-type time-of-flight electron spectrometer. The resulting photoelectron distributions from Al n, Ni n, Ag n and Sn n, n < 22, are compared; all spectra display a dramatic dependence on the cluster size and differ substantially from the respective bulk spectra. The measurements provide information about low-lying excited electronic structures which are missing in the solid metal. Photoelectron thresholds as estimates of electron affinities in part follow a simple electrostatic model.
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GANTEFÖR, Gerd, Michael GAUSA, Karl-Heinz MEIWES-BROER, Hans O. LUTZ, 1988. Ultraviolet photodetachment spectroscopy on jet-cooled metal-cluster anions. In: Faraday Discussions of the Chemical Society. 1988, 86, pp. 197-208. Available under: doi: 10.1039/DC9888600197BibTex
@article{Gantefor1988Ultra-5349,
year={1988},
doi={10.1039/DC9888600197},
title={Ultraviolet photodetachment spectroscopy on jet-cooled metal-cluster anions},
volume={86},
journal={Faraday Discussions of the Chemical Society},
pages={197--208},
author={Ganteför, Gerd and Gausa, Michael and Meiwes-Broer, Karl-Heinz and Lutz, Hans O.}
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<dcterms:abstract xml:lang="eng">Metal-cluster anions have been produced by laser vaporization and cooled in a supersonic expansion, without converting neutral clusters into anions via a secondary ionizing agent. After mass-selection, photoelectrons were detached (h= 3.68 eV) from defined anion bunches and analysed in a magnetic bottle-type time-of-flight electron spectrometer. The resulting photoelectron distributions from Al n, Ni n, Ag n and Sn n, n < 22, are compared; all spectra display a dramatic dependence on the cluster size and differ substantially from the respective bulk spectra. The measurements provide information about low-lying excited electronic structures which are missing in the solid metal. Photoelectron thresholds as estimates of electron affinities in part follow a simple electrostatic model.</dcterms:abstract>
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