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Ultraviolet photodetachment spectroscopy on jet-cooled metal-cluster anions

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FaraDisChem861988.pdf
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1988

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Gausa, Michael
Meiwes-Broer, Karl-Heinz
Lutz, Hans O.

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Faraday Discussions of the Chemical Society. 1988, 86, pp. 197-208. Available under: doi: 10.1039/DC9888600197

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Metal-cluster anions have been produced by laser vaporization and cooled in a supersonic expansion, without converting neutral clusters into anions via a secondary ionizing agent. After mass-selection, photoelectrons were detached (h= 3.68 eV) from defined anion bunches and analysed in a magnetic bottle-type time-of-flight electron spectrometer. The resulting photoelectron distributions from Al n, Ni n, Ag n and Sn n, n < 22, are compared; all spectra display a dramatic dependence on the cluster size and differ substantially from the respective bulk spectra. The measurements provide information about low-lying excited electronic structures which are missing in the solid metal. Photoelectron thresholds as estimates of electron affinities in part follow a simple electrostatic model.

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530 Physik

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ISO 690GANTEFÖR, Gerd, Michael GAUSA, Karl-Heinz MEIWES-BROER, Hans O. LUTZ, 1988. Ultraviolet photodetachment spectroscopy on jet-cooled metal-cluster anions. In: Faraday Discussions of the Chemical Society. 1988, 86, pp. 197-208. Available under: doi: 10.1039/DC9888600197
BibTex
@article{Gantefor1988Ultra-5349,
  year={1988},
  doi={10.1039/DC9888600197},
  title={Ultraviolet photodetachment spectroscopy on jet-cooled metal-cluster anions},
  volume={86},
  journal={Faraday Discussions of the Chemical Society},
  pages={197--208},
  author={Ganteför, Gerd and Gausa, Michael and Meiwes-Broer, Karl-Heinz and Lutz, Hans O.}
}
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