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Magnetic-field-enhanced radical yield from triplet electron-transfer reaction in reversed micelles

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1983

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Schlenker, Wolfgang
Ulrich, Thomas

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Chemical Physics Letters. 1983, 103(2), pp. 118-123. ISSN 0009-2614. Available under: doi: 10.1016/0009-2614(83)87477-6

Zusammenfassung

The radical yield in the electron-transfer reaction between thionine triplet and aniline in reversed micelles is increased by an external magnetic field. The saturation value of the effect amounts to 85% (18 kG) and the B1/2 value is 300 G. The magnetic-field effect is discussed on the basis of the radical-pair mechanism with a quantitative consideration of the hyperfine-induced spin motion.

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540 Chemie

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ISO 690SCHLENKER, Wolfgang, Thomas ULRICH, Ulrich STEINER, 1983. Magnetic-field-enhanced radical yield from triplet electron-transfer reaction in reversed micelles. In: Chemical Physics Letters. 1983, 103(2), pp. 118-123. ISSN 0009-2614. Available under: doi: 10.1016/0009-2614(83)87477-6
BibTex
@article{Schlenker1983Magne-9567,
  year={1983},
  doi={10.1016/0009-2614(83)87477-6},
  title={Magnetic-field-enhanced radical yield from triplet electron-transfer reaction in reversed micelles},
  number={2},
  volume={103},
  issn={0009-2614},
  journal={Chemical Physics Letters},
  pages={118--123},
  author={Schlenker, Wolfgang and Ulrich, Thomas and Steiner, Ulrich}
}
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