Publikation: Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca]
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1995
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Angewandte Chemie International Edition in English. 1995, 34(7), pp. 791-793. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.199507911
Zusammenfassung
The exothermic formation of a Ca–CO complex [Eq.(a), ΔHo = −25 kJ mol−1] confirms that CO can bind to a metal center without π back donation from filled d orbitals. In its spectroscopic properties, the calcocene–carbonyl complex resembles "nonclassical" noble metal carbonyl complexes. Cp* = η5-C5Me5.
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540 Chemie
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Alkaline earth metal compounds, carbonyl complexes, high-pressure chemistry, metallocenes
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SELG, Peter, Hans-Herbert BRINTZINGER, Richard A. ANDERSEN, István T. HORVÁTH, 1995. Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca]. In: Angewandte Chemie International Edition in English. 1995, 34(7), pp. 791-793. ISSN 0570-0833. eISSN 1521-3773. Available under: doi: 10.1002/anie.199507911BibTex
@article{Selg1995Coord-23928, year={1995}, doi={10.1002/anie.199507911}, title={Coordination of CO to the alkaline earth metallocene [(Me<sub>5</sub>C<sub>5</sub>)<sub>2</sub>Ca]}, number={7}, volume={34}, issn={0570-0833}, journal={Angewandte Chemie International Edition in English}, pages={791--793}, author={Selg, Peter and Brintzinger, Hans-Herbert and Andersen, Richard A. and Horváth, István T.} }
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