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Adsorption and Decomposition of DMMP on Size‐Selected (WO3)3 Clusters

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2018

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Tang, Xin
Hicks, Zachary
Eichhorn, Bryan W.
Bowen, Kit H.

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https://doi.org/10.1002/slct.201800229
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ChemistrySelect. 2018, 3(13), pp. 3718-3721. eISSN 2365-6549. Available under: doi: 10.1002/slct.201800229

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The adsorption and decomposition behaviors of dimethyl methylphosphate (DMMP) on size‐selected (WO3)3 clusters were studied by a combination of X‐ray Photoelectron Spectroscopy (XPS) and Temperature Programmed Reaction (TPR). The fate of DMMP adsorbed on (WO3)3 clusters was found to be very similar to its fate on (MoO3)3. In contrast to DMMP on (MoO3)3, however, dimethyl ether was observed as a product in the reaction of DMMP with (WO3)3, in addition to methanol, due to the higher Lewis acidity of (WO3)3 clusters as compared to (MoO3)3.

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ISO 690TANG, Xin, Zachary HICKS, Gerd GANTEFÖR, Bryan W. EICHHORN, Kit H. BOWEN, 2018. Adsorption and Decomposition of DMMP on Size‐Selected (WO3)3 Clusters. In: ChemistrySelect. 2018, 3(13), pp. 3718-3721. eISSN 2365-6549. Available under: doi: 10.1002/slct.201800229
BibTex
@article{Tang2018-04-09Adsor-42300,
  year={2018},
  doi={10.1002/slct.201800229},
  title={Adsorption and Decomposition of DMMP on Size‐Selected (WO<sub>3</sub>)<sub>3</sub> Clusters},
  number={13},
  volume={3},
  journal={ChemistrySelect},
  pages={3718--3721},
  author={Tang, Xin and Hicks, Zachary and Ganteför, Gerd and Eichhorn, Bryan W. and Bowen, Kit H.}
}
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