Publikation: Palladium-catalyzed coupling of 2,2'- dihalobiaryls with metallated cyclopentenes : An easy synthesis for spiro[cyclopentene-1,9'-[9H]fluorene]s
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1993
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Tetrahedron Letters. 1993, 34(22), pp. 3551-3554. ISSN 0040-4039. eISSN 1873-3581. Available under: doi: 10.1016/S0040-4039(00)73633-1
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In the presence of palladium catalysts, one of the two carbons attached to halogen in 2,2'-diiodobiphenyl couples with unsaturated organometallics, after which the other adds to the newly incorporated double bond. Spiro[cyclopentene-1,9'-[9H]fluorene]s can be synthesized in this way.
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KATZ, Thomas J., Adam M. GILBERT, Monika E. HUTTENLOCH, Gu MIN-MIN, Hans-Herbert BRINTZINGER, 1993. Palladium-catalyzed coupling of 2,2'- dihalobiaryls with metallated cyclopentenes : An easy synthesis for spiro[cyclopentene-1,9'-[9H]fluorene]s. In: Tetrahedron Letters. 1993, 34(22), pp. 3551-3554. ISSN 0040-4039. eISSN 1873-3581. Available under: doi: 10.1016/S0040-4039(00)73633-1BibTex
@article{Katz1993Palla-23939, year={1993}, doi={10.1016/S0040-4039(00)73633-1}, title={Palladium-catalyzed coupling of 2,2'- dihalobiaryls with metallated cyclopentenes : An easy synthesis for spiro[cyclopentene-1,9'-[9H]fluorene]s}, number={22}, volume={34}, issn={0040-4039}, journal={Tetrahedron Letters}, pages={3551--3554}, author={Katz, Thomas J. and Gilbert, Adam M. and Huttenloch, Monika E. and Min-Min, Gu and Brintzinger, Hans-Herbert} }
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