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Palladium-catalyzed coupling of 2,2'- dihalobiaryls with metallated cyclopentenes : An easy synthesis for spiro[cyclopentene-1,9'-[9H]fluorene]s

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Katz_239396.pdf
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1993

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Katz, Thomas J.
Gilbert, Adam M.
Huttenloch, Monika E.
Min-Min, Gu

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Tetrahedron Letters. 1993, 34(22), pp. 3551-3554. ISSN 0040-4039. eISSN 1873-3581. Available under: doi: 10.1016/S0040-4039(00)73633-1

Zusammenfassung

In the presence of palladium catalysts, one of the two carbons attached to halogen in 2,2'-diiodobiphenyl couples with unsaturated organometallics, after which the other adds to the newly incorporated double bond. Spiro[cyclopentene-1,9'-[9H]fluorene]s can be synthesized in this way.

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540 Chemie

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ISO 690KATZ, Thomas J., Adam M. GILBERT, Monika E. HUTTENLOCH, Gu MIN-MIN, Hans-Herbert BRINTZINGER, 1993. Palladium-catalyzed coupling of 2,2'- dihalobiaryls with metallated cyclopentenes : An easy synthesis for spiro[cyclopentene-1,9'-[9H]fluorene]s. In: Tetrahedron Letters. 1993, 34(22), pp. 3551-3554. ISSN 0040-4039. eISSN 1873-3581. Available under: doi: 10.1016/S0040-4039(00)73633-1
BibTex
@article{Katz1993Palla-23939,
  year={1993},
  doi={10.1016/S0040-4039(00)73633-1},
  title={Palladium-catalyzed coupling of 2,2'- dihalobiaryls with metallated cyclopentenes : An easy synthesis for spiro[cyclopentene-1,9'-[9H]fluorene]s},
  number={22},
  volume={34},
  issn={0040-4039},
  journal={Tetrahedron Letters},
  pages={3551--3554},
  author={Katz, Thomas J. and Gilbert, Adam M. and Huttenloch, Monika E. and Min-Min, Gu and Brintzinger, Hans-Herbert}
}
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