Publikation:

Synthesis of Stable Aragonite Superstructures by a Biomimetic Crystallization Pathway

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2005

Autor:innen

Nassif, Nadine
Gehrke, Nicole
Pinna, Nicola
Shirshova, Natasha
Tauer, Klaus
Antonietti, Markus
Cölfen, Helmut

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https://doi.org/10.1002/anie.200500081
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Chemie: Publikationen
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Published

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Angewandte Chemie International Edition. 2005, 44(37), pp. 6004-6009. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200500081

Zusammenfassung

Selective nucleation of aragonite can be achieved at ambient conditions in water by using block copolymer microgels at a very low concentration (0.1 ppm). One polymer template particle is sufficient to control the nucleation of a ring of aragonite single crystals, which propagate into a sheaf structure (see SEM image). Each aragonite crystal is protected by an outer amorphous layer that results in prolonged stability of the aragonite.

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540 Chemie

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ISO 690NASSIF, Nadine, Nicole GEHRKE, Nicola PINNA, Natasha SHIRSHOVA, Klaus TAUER, Markus ANTONIETTI, Helmut CÖLFEN, 2005. Synthesis of Stable Aragonite Superstructures by a Biomimetic Crystallization Pathway. In: Angewandte Chemie International Edition. 2005, 44(37), pp. 6004-6009. ISSN 1433-7851. eISSN 1521-3773. Available under: doi: 10.1002/anie.200500081
BibTex
@article{Nassif2005-09-19Synth-40267,
  year={2005},
  doi={10.1002/anie.200500081},
  title={Synthesis of Stable Aragonite Superstructures by a Biomimetic Crystallization Pathway},
  number={37},
  volume={44},
  issn={1433-7851},
  journal={Angewandte Chemie International Edition},
  pages={6004--6009},
  author={Nassif, Nadine and Gehrke, Nicole and Pinna, Nicola and Shirshova, Natasha and Tauer, Klaus and Antonietti, Markus and Cölfen, Helmut}
}
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